CuCe1-xMnxOy复合氧化物催化氧化碳烟颗粒性能的研究  

Study on catalytic performance of CuCe1-xMnxOy composite for oxidation of soot particles

作　　者：夏永康 崔冰 闫帅 陈秉辉[1] 刘运权 王夺 叶跃元 李水荣 XIA Yong-kang;CUI Bing;YAN Shuai;CHEN Bing-hui;LIU Yun-quan;WANG Duo;YE Yue-yuan;LI Shui-rong(National Engineering Laboratory for Green Chemical Production of Alcohols-Ethers-Esters,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361102,China;College of Energy,Xiamen University,Xiamen 361102,China)

机构地区：[1]厦门大学化学化工学院,醇醚酯化工清洁生产国家工程实验室,福建厦门361102 [2]厦门大学能源学院,福建厦门361102

出　　处：《现代化工》2019年第12期150-155,共6页Modern Chemical Industry

基　　金：福建省自然科学基金(2015J05033);厦门大学校长基金(20720170043)

摘　　要：利用反向共沉淀法合成CuCe1-xMnxOy复合氧化物催化剂,X射线衍射分析(XRD)和拉曼(Raman)表征结果表明,反向共沉淀法可以将Cu、Mn离子在CeO2晶格中有效掺杂并形成晶体粒径较小的固溶体。程序升温还原(H2-TPR)与X射线光电子能谱(XPS)表征结果表明,Cu、Mn、Ce之间存在强相互作用,有效提升了氧化物的氧化还原性能。所合成的CuCe1-xMnxOy复合氧化物系列催化剂在碳烟颗粒催化氧化中均表现出良好的反应活性,其中CuCe0.8Mn0.2催化剂表现出最佳活性,T50仅为354℃,并且在循环测试中也基本保持稳定。A series of CuCe1-xMnxOy composites are prepared by reverse co-precipitation method.The results by X-ray diffraction analysis(XRD)and Raman analysis reveal the successful incorporation of Cu and Mn cations into the ceria framework through the reverse co-precipitation method,which induces a reduced crystal size of CeO2 in the asprepared composites.The H2-temperature programmed reduction(H2-TPR)and X-ray photoelectron spectroscopy(XPS)analysis indicates the presence of strong interaction between Cu,Mn and Ce cations,which shows positive impact on the redox property of the samples.All CuCe1-xMnxOy composites show high catalytic activity towards soot oxidation.Particularly,CuCe0.8Mn0.2 shows the best catalytic activity with a T50 of 354℃and also a good stability in the repeated tests.

关 键 词：碳烟颗粒 催化氧化 CuCe1-xMnxOy 

分 类 号：X513[环境科学与工程—环境工程]