直线型铂炔化合物的合成及其成凝胶性能研究  

Synthesis and Gelation Properties of Linear Platinum Alkyne Compounds

作　　者：范建强 曾旺 徐潇 杨凌辉 余威 张灯青[1] Fan Jian-qiang;Zeng Wang;Xu Xiao;Yang Ling-hui;Yu Wei;Zhang Deng-qing(College of Chemistry,Chemical Engineering and Biotechnology,Donghua University,Shanghai 201600)

机构地区：[1]东华大学化学化工与生物工程学院

出　　处：《生物化工》2019年第6期45-49,共5页Biological Chemical Engineering

摘　　要：本文以伯胺类化合物为起始原料,经4步反应合成了直线型铂炔化合物1d,其结构经1H NMR、13C NMR及HR-MS(ESI)表征,并对其成凝胶性能进行研究,结果表明:1d只在低极性溶剂甲基环己烷中形成黄色透明凝胶,利用扫描电子显微镜可以观察到不规则的低聚体结构。In this paper, a linear platinum alkyne compound 1 d was synthesized by a four-step reaction using a primary amine compound. The structure was characterized by 1 H NMR, 13C NMR and HR-MS(ESI), and its gelation performance was studied. The results showed that 1 d gave yellow translucent organogels in methylcyclohexane, the morphologies of 1 d featured irregular agglomerates.

关 键 词：铂炔化合物 酰胺化 Sonogashira-Hagihara偶联 氢键 

分 类 号：O621.2[理学—有机化学]