新型复合氮-磷-硫阻燃剂对于竹基材料的阻燃效果研究  

Effect of a New Composite Nitrogen-Phosphorus-Sulfur Flame Retardant on Bamboo-based Materials

作　　者：金满洁 王发鹏 吕森强 袁华 范红伟 林鹏 黄建颖 余其中 陈虹 楼斌 庞久寅[3] 汤玉训 Jin Manjie;Wang Fapeng;Lv Senqiang;Yuan Hua;Fan Hongwei;Lin Peng;Huang Jianying;Yu Qizhong;Chen Hong;Lou Bin;Pang Jiuyin;Tang Yuxun(Hangzhou Iron&Steel Group Co.,Ltd,Zhonghang Monitoring&Testing Technology Research Institute Co.,Ltd,Hangzhou 310000,China;Zhejiang University,School of Materials Science and Engineering,Hangzhou 310000,China;Beihua University,Jilin Wood-based Materials Science and Engineering Key Laboratories,Jilin,132013,China)

机构地区：[1]杭州钢铁集团有限公司中杭监测技术研究院有限公司,杭州310022 [2]浙江大学材料科学与工程学院,杭州310000 [3]北华大学吉林省木质材料科学与工程重点实验室,吉林省吉林市132013

出　　处：《世界竹藤通讯》2019年第6期21-24,共4页World Bamboo and Rattan

基　　金：国家自然科学基金资助项目(31270589)

摘　　要：本研究采用低聚合度的聚磷酸铵(APP)与无水对氨基苯磺酸(ASA)通过离子交换反应制备一种用于竹基材料的复合阻燃剂——氮-磷-硫(N-P-S)复合阻燃剂。其原理为经脱水缩合的磷酸盐通过交联促使竹基材料表层炭化,同时成为强脱水剂及不燃气体覆盖竹材,从而隔绝或稀释氧气浓度达到阻燃的效果。试验结果显示,随着浸渍N-P-S时间的增加,竹材的载药量呈现出先上升后趋于稳定的趋势,浸渍24 h后竹材的阻燃时间达到207.69 s,是浸泡蒸馏水的3.25倍。N-P-S阻燃剂属于无卤的绿色环保新型阻燃剂,可为竹材阻燃改性提供研究经验。A new composite flame retardant for bamboo-based materials is prepared by ion exchange reaction with the ammonium polyphosphate(APP)with a low degree of polymerization and anhydrous p-aminobenzenesulfonic acid(ASA)in this study.The principle is that the dehydrated and condensed phosphates promote the surface carbonization of bamboo based materials through cross-linking,and at the same time become strong dehydrating agent and non-combustible gas to cover the bamboo surface,so as to isolate or dilute oxygen concentration to achieve the effect of flame retardant.The results show that with the increase of impregnation time in N-P-S,the drug loading of bamboo increases first and then tends to be stable.After 24 hours of impregnation,the flame retardant time of bamboo reaches 207.69 s,which is 3.25 times of that of distilled water.N-P-S flame retardant is a new type of halogen-free environmental friendly flame retardant,which can provide research experiences for flame retardant modification of bamboo.

关 键 词：竹基材料 聚磷酸铵 无水对氨基苯磺酸 复合阻燃剂 

分 类 号：TQ3[化学工程]