微量Sr对Mg-0.2Zn-0.1Mn-xSr医用可降解镁合金显微组织、力学性能及腐蚀性能的影响  

Effects of Trace Sr on Microstructure, Mechanical Properties and Corrosion Resistance of Mg-0.2Zn-0.1Mn-xSr Biomaterials

作　　者：余伟铭 李静媛[1] 李建兴[1] 王瑾[1] 赖慧颖 张源[1] Yu Weiming;Li Jingyuan;Li Jianxing;Wang Jin;Lai Huiying;Zhang Yuan(University of Science and Technology Beijing,Beijing 100083,China)

机构地区：[1]北京科技大学

出　　处：《稀有金属材料与工程》2019年第12期4016-4025,共10页Rare Metal Materials and Engineering

基　　金：国家重点研发计划（2018YFB0704102）

摘　　要：主要研究了在Mg-0.2Zn-0.1Mn中添加微量的Sr后,Mg-0.2Zn-0.1Mn-x Sr(x=0.1,0.2,0.3)合金显微组织、力学性能及耐腐蚀性能的变化。显微组织观察结果表明,随着Sr含量增加,晶粒尺寸明显降低;Mg17Sr2相在镁基体中呈颗粒状均匀弥散分布,且Mg17Sr2相体积随着Sr含量增加而长大。室温拉伸试验结果表明,微量的Sr能够提高镁合金的抗拉强度和屈服强度,但延伸率却表现出下降的趋势。通过Kokubo模拟体液中的浸泡实验了解镁合金的降解行为。失重实验测得Mg-0.2Zn-0.1Mn-x Sr (x=0,0.1,0.2,0.3)腐蚀速率为:6.85、6.01、6.80和7.52 mm/a。微量Sr的添加能够提高镁合金的耐腐蚀性能;但随着Sr含量增加,镁合金更容易产生点蚀和晶间腐蚀,反而使镁合金耐腐蚀性能出现降低。这是因为添加微量Sr后镁合金晶粒细化,细小而弥散分布的Mg17Sr2相有助于腐蚀产物膜沉积形成对基体的保护,使得镁合金更耐蚀。而过大的Mg17Sr2相会加剧局部的微电偶腐蚀,破坏腐蚀产物膜,降低镁合金的耐腐蚀性能。结果表明Mg-0.2Zn-0.1Mn-0.1Sr具有最佳的力学性能和耐腐蚀性能配比。The effects of adding trace Sr element on microstructure, mechanical properties and corrosion properties of Mg-0.2 Zn-0.1 Mn-x Sr(x=0, 0.1, 0.2, 0.3, wt%) alloys were investigated. The results of microstructure observation reveal that the grain size of the alloy decreases with the increase of Sr content. The granular Mg17 Sr2 phase is uniformly dispersed in the magnesium matrix, while the second phase grows up as the Sr increases. The results of mechanical properties investigated by tensile test at room temperature indicate that micro Sr can improve the yield strength and tensile strength. But the elongation decreases with the increase of Sr content. Degradation was studied using immersion tests in Kokubo solution. The corrosion rate is faster and the pitting is more likely to occur when the Sr content increases. The average corrosion rates of Mg-0.2 Zn-0.1 Mn-x Sr(x=0, 0.1, 0.2, 0.3, wt%) measured by mass loss are 6.85→6.01→6.80→7.52 mm/a. Trace Sr can improve the corrosion resistance of magnesium alloys. However, with the increase of Sr content, the magnesium alloys are more prone to pitting and intergranular corrosion, which in turn reduces the corrosion resistance of magnesium alloys. The bio-corrosion behaviors can be attributed to the grain refinement and the diffused second phase, which can promote the formation of corrosion product film. However, the bigger second phase in the matrix will accelerate the local corrosion, and reduce the corrosion resistance of magnesium alloy. The results show that Mg-0.2 Zn-0.1 Mn-0.1 Sr has the best mechanical properties and corrosion resistance.

关 键 词：镁合金 锶 显微组织 机械性能 耐腐蚀性能 

分 类 号：TG146.22[一般工业技术—材料科学与工程] TG178.2[金属学及工艺—金属材料]