肉桂腈的绿色合成及发光性能研究  

Green synthesis of cinnamonitrile and study of its luminescence properties

作　　者：肖尊宏[1] XIAO Zunhong(School of Chemistry and Materials Science,Guizhou Normal University,Guiyang,Guizhou 550025,China)

机构地区：[1]贵州师范大学化学与材料科学学院

出　　处：《贵州师范大学学报（自然科学版）》2020年第1期21-24,共4页Journal of Guizhou Normal University：Natural Sciences

基　　金：贵州省科技基金项目(黔科合J[2011]2077)

摘　　要：以肉桂醛、盐酸羟胺为原料,"一锅煮法"合成了肉桂腈,通过红外光谱(IR)、~1H NMR、紫外光谱(UV)、元素分析对化合物进行了表征,所合成的化合物是我们的目标化合物肉桂腈。荧光光谱表明:固体肉桂腈在363 nm紫外光激发下发出405~500 nm范围内的强蓝光,与作物光合作用所需要的蓝光420~480 nm左右相吻合,是一种潜在的用于蓝光转换的材料。Cinnamonitrile was synthesized with benzaldehyde and acetonitrile by one pot way.Cinnamonitrile was characterized by IR, ~1H NMR, UV and element analysis. The synthesized compound is our target compound cinnamonitrile. Fluorescence spectra showed that solid state cinnamonitrile emits strong blue light at 405~500 nm under excited at 363 nm.The blue light of cinnamonitrile is fit for plants photosynthesis(about 420~480 nm) and cinnamonitrile will be a kind of potential blue light-conversion material.

关 键 词：肉桂腈 绿色合成 蓝光转换材料 

分 类 号：O612[理学—无机化学]