由醚氧桥连四羧酸配体构筑的锰(Ⅱ)和锌(Ⅱ)配位聚合物的合成、晶体结构、荧光及磁性质（英文）  

Syntheses,Crystal Structures,Luminescent and Magnetic Properties of 2D Manganese(Ⅱ) and Zinc(Ⅱ) Coordination Polymers Based on an Ether-Bridged Tetracarboxylic Acid

作　　者：黎彧 赵振宇 邹训重 冯安生 顾金忠 LI Yu;ZHAO Zhen-Yu;ZOU Xun-Zhong;FENG An-Sheng;GU Jin-Zhong(Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology,Guangdong Industry Polytechnic,Guangzhou 510300,China;School of Intelligent Manufacturing and Equipment,Shenzhen Institute of Information Technology,Shenzhen,Guangdong 518172,China;College of Chemistry and Chemical Engineering,Lanzhou University,Lanzhou 730000,China)

机构地区：[1]广东轻工职业技术学院广东省特种建筑材料及其绿色制备工程技术研究中心/佛山市特种功能性建筑材料及其绿色制备技术工程中心 [2]深圳信息职业技术学院智能制造与装备学院 [3]兰州大学化学化工学院

出　　处：《无机化学学报》2020年第2期377-384,共8页Chinese Journal of Inorganic Chemistry

基　　金：广东省高等职业院校珠江学者岗位计划资助项目(2015,2018);广东轻院珠江学者人才类项目(No.RC2015-001),广东轻院科技成果培育项目(No.KJPY2018-010);广东轻院优秀青年基金项目(No.QN2018-007)资助;生物无机与合成化学教育部重点实验室开放基金(2016);广东省高校创新团队项目(No.2017GKCXTD001);广州市科技计划项目(No.201904010381);深圳市科技计划项目(No.JCYJ20170817112445033,GGFW2017041209483817);广东省大学生科技创新培育专项(No.pdjh2019b0690)

摘　　要：采用水热方法,用醚氧桥连四羧酸配体(H4L)和菲咯啉(phen)、吡啶(py)分别与MnCl2·4H2O和ZnCl2反应,合成了2个二维配位聚合物{[Mn2(μ6-L)(phen)2]·5H2O}n(1)和{[Zn2(μ7-L)(py)]·H2O}n(2),并对其结构、荧光和磁性质进行了研究。结构分析结果表明2个配合物分别属于三斜和单斜晶系,P1和I2/a空间群。配合物1和2分别具有基于四核锰和双核锌的二维层结构。荧光和磁性研究结果表明,配合物2在室温下能发出蓝色荧光,聚合物1中相邻Mn?髤离子间存在反铁磁相互作用。Two 2D manganese(Ⅱ)and zinic(Ⅱ)coordination polymers,namely{[Mn2(μ6-L)(phen)2]·5H2O}n(1)and{[Zn2(μ7-L)(py)]·H2O}n(2),have been constructed hydrothermally using H4L(H4L=3,3′,4,5′-diphenyl ether tetra-carboxylic acid),phen(phen=1,10-phenanthroline),py(py=pyridine),and manganese or zinc chlorides.Single-crystal X-ray diffraction analyses revealed that two complexes crystallize in the triclinic or monoclinic systems,space groups P1 or I2/a.Both complexes feature a 2D sheet structure based on Mn4 or Zn2 subunits.The luminescent and magnetic properties for two complexes were also investigated.The results of fluorescence and magnetic studies show that complex 2 can emit blue fluorescence at room temperature,and antiferromagnetic interactions exist between adjacent Mn(Ⅱ)ions in polymer 1.CCDC:1943370,1;1943371,2.

关 键 词：配位聚合物 醚氧桥连四羧酸配体 荧光 磁性 

分 类 号：O614.711[理学—无机化学] O614.241[理学—化学]