以水为溶剂的铃木-宫浦偶联反应最新研究进展  

Recent Progress in the Suzuki-Miyaura Cross-Coupling Reactions in Water

作　　者：徐鹏[1] 段新红[1] Xu Peng;Duan Xinhong(College of Science,Beijing Forestry University,Beijing 100083)

机构地区：[1]北京林业大学理学院

出　　处：《有机化学》2019年第12期3315-3327,共13页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.21671021)资助项目~~

摘　　要：过渡金属催化的铃木-宫浦偶联反应是目前构建碳-碳键最为重要的有机手段之一,人们对以水为溶剂的绿色有机反应日益重视,在水介质中进行铃木-宫浦偶联反应已成为人们研究和开发的热点.就近年来在水介质中进行均相和非均相催化铃木-宫浦偶联反应的进展加以综述,并展望了其应用前景.Transition-metal-catalyzed Suzuki-Miyaura cross-coupling is one of the most powerful transformations for C-C biaryl bond formation at present. With the increasing demand for green chemistry, water as solvent for the Suzuki-Miyaura cross-coupling reactions has been of widespread interest. The literature in recent years on the Suzuki-Miyaura cross-coupling reactions by heterogeneous or homogeneous catalysis in water is reviewed, and their perspectives for further developments are also presented.

关 键 词：铃木-宫浦偶联 水为溶剂 非均相催化 均相催化 

分 类 号：O621.251[理学—有机化学]