水热合成Ba3Sc2F12:Yb3+,Er3+荧光粉的形貌及其上转换发光性能的探究  

Research on Morphology and Up-conversion Luminescence Properties of Ba3Sc2F12:Yb3+,Er3+ Phosphors of Hydrothermal Synthesis

作　　者：毛旖旎 杨骏[1] MAO Yi-ni;YANG Jun(School of Chemistry and Chemical Engineering,Southwest University,Chongqing 400715,China)

机构地区：[1]西南大学化学化工学院

出　　处：《聊城大学学报（自然科学版）》2020年第2期68-72,共5页Journal of Liaocheng University:Natural Science Edition

基　　金：国家自然科学基金项目（51302229）资助

摘　　要：采用简单温和的水热法合成了Ba3Sc2F12:14%Yb^3+,2%Er ^3+荧光粉,通过控制反应时间和Li^+离子的掺杂量获得了一系列产品,对其物相组成及微观形貌进行了具体的分析,同时基于以上两个因素分别对所制得的产品的发光性能进行了探究,结果表明,反应时间的延长会使得产品晶体的尺寸增大进而使得发光强度增加,Li^+离子的掺杂量为40%时产品的发光强度最大.Ba3Sc2F12:14%Yb^3+,2%Er 3+phosphors were synthesized via a simple mild hydrothermal method.A series of samples were obtained by controlling the reaction time and the doping concentration of Li^+ions,and their phase and morphology were analyzed in detail.At the same time,the analysis of the luminescence properties of the prepared products was carried out based on the above two factors.And the results show that the extension of the reaction time will increase the size of the crystals and increase the luminescence intensity.In addition,the maximum luminescence intensity is obtained when the doping amount of Li^+ions was 40%.

关 键 词：Ba3Sc2F12 荧光粉 水热合成 发光性能 形貌 影响因素 

分 类 号：O644.1[理学—物理化学]