Hygroscopicity measurement of sodium carbonate,β-alanine and internally mixed β-alanine/Na2CO3 particles by ATR-FTIR  

作　　者：Ping Yang Hui Yang Na Wang Chunyun Du Shufeng Pang Yunhong Zhang 

机构地区：[1]School of Chemistry and Chemical Engineering,Beijing Institute of Technology

出　　处：《Journal of Environmental Sciences》2020年第1期250-259,共10页环境科学学报（英文版）

基　　金：supported by the National Natural Science Foundation of China(Nos.91644101,91544223 and 21373026)

摘　　要：Water-uptakes of pure sodium carbonate(Na2CO3),pureβ-alanine and internally mixedβ-alanine/Na2CO3 aerosol particles with different mole ratios are first monitored using attenuated total reflectance Fourier transform infrared spectroscopy(ATR-FTIR)technique.For pure Na2CO3 aerosol particles,combining the absorptions at 877 and 1422 cm-1 with abrupt water loss shows the efflorescence relative humidity(ERH)of 62.9%–51.9%.Upon humidifying,solid Na2CO3 firstly absorbs water to from Na2CO3·H2O crystal at 72.0%RH and then deliquesces at 84.5%RH(DRH).As for pureβ-alanine particles,the crystallization takes place in the range of 42.4%–33.2%RH and becomes droplets at^88.2%RH.Whenβ-alanine is mixed with Na2CO3 at various mole ratios,it shows no efflorescence of Na2CO3 whenβ-alanine to Na2CO3 mole ratio(OIR)is 2:1.For 1:1 and 1:2β-alanine/Na2CO3 aerosols,the ERHs of Na2CO3 are 51.8%–42.3%and 57.1%–42.3%,respectively.Whileβ-alanine crystal appears from 62.7%RH for 2:1 and 59.4%RH for both 1:1 and 1:2 particles and lasts to driest state.On hydration,the DRH is 44.7%–75.2%for Na2CO3 with the OIR of 1:1 and 44.7%–69.0%for 1:2 mixture,and those of β-alanine are 74.8% for 2:1 mixture and 68.9%for two others.After the first dehumidification–humidification,all the water contents decrease despite of constituent fraction.And at^92%RH,the remaining water contents are 92%,89%and 82%at^92%RH,corresponding to OIR of 2:1,1:1 and 1:2 mixed system,respectively.Water-uptakes of pure sodium carbonate（Na2CO3）,pure β-alanine and internally mixedβ-alanine/Na2CO3 aerosol particles with different mole ratios are first monitored using attenuated total reflectance Fourier transform infrared spectroscopy（ATR-FTIR） technique.For pure Na2CO3 aerosol particles,combining the absorptions at 877 and 1422 cm-1 with abrupt water loss shows the efflorescence relative humidity（ERH） of 62.9%–51.9%.Upon humidifying,solid Na2CO3 firstly absorbs water to from Na2CO3·H2 O crystal at 72.0% RH and then deliquesces at 84.5% RH（DRH）.As for pure β-alanine particles,the crystallization takes place in the range of 42.4%–33.2% RH and becomes droplets at ～ 88.2% RH.When β-alanine is mixed with Na2CO3 at various mole ratios,it shows no efflorescence of Na2CO3 whenβ-alanine to Na2CO3 mole ratio（OIR） is 2:1.For 1:1 and 1:2 β-alanine/Na2CO3 aerosols,the ERHs of Na2CO3 are 51.8%–42.3% and 57.1%–42.3%,respectively.While β-alanine crystal appears from 62.7% RH for 2:1 and 59.4% RH for both 1:1 and 1:2 particles and lasts to driest state.On hydration,the DRH is 44.7%–75.2% for Na2CO3 with the OIR of 1:1 and 44.7%–69.0%for 1:2 mixture,and those of β-alanine are 74.8% for 2:1 mixture and 68.9% for two others.After the first dehumidification–humidification,all the water contents decrease despite of constituent fraction.And at ～ 92% RH,the remaining water contents are 92%,89% and 82%at ～ 92% RH,corresponding to OIR of 2:1,1:1 and 1:2 mixed system,respectively.

关 键 词：Sodium carbonate Β-ALANINE HYGROSCOPICITY CRYSTALLIZATION Immune effects DELIQUESCENCE 

分 类 号：X831[环境科学与工程—环境工程]