疏水性纤维素纳米纤丝气凝胶的制备及性能研究  

Preparation and characterization of hydrophobic cellulose nanofibril aerogels

作　　者：郜梦茜 张慧[1] 陈甜甜 樊丽 温洋兵[1] 刘鹏涛[1,2] 刘忠 GAO Mengxi;ZHANG Hui;CHEN Tiantian;FAN Li;WEN Yangbing;LIU Pengtao;LIU Zhong(Tianjin Key Laboratory of Pulping and Papermaking, Tianjin University of Science and Technology,Tianjin 300457, China;State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology,Shandong Academy of Sciences, Jinan 250353, China)

机构地区：[1]天津科技大学天津市制浆造纸重点实验室,天津300457 [2]齐鲁工业大学(山东省科学院)生物基材料与绿色造纸国家重点实验室,济南250353

出　　处：《功能材料》2020年第2期2107-2112,共6页Journal of Functional Materials

基　　金：国家重点研发计划重点专项资助项目(2017YFB0307902);天津市教委科研计划资助项目(2018KJ098);生物基材料与绿色造纸国家重点实验室开放基金资助项目(KF201809);天津科技大学青年教师创新基金资助项目(2017LG06)

摘　　要：以TEMPO氧化纤维素纳米纤丝为原料,甲基三甲氧基硅烷为改性剂,N,N-亚甲基双丙烯酰胺(MBA)为交联剂,采用溶胶凝胶法与冷冻干燥法制备出疏水纤维素纳米纤丝气凝胶。在通过对反应条件的探讨后发现,当温度为55℃,pH值=8,改性剂添加量为3 mL,反应时间在5 h以上时可以得到低密度(<0.03 g/cm3)、高孔隙率(>98%)的气凝胶,其接触角可达130°,吸油量达到气凝胶本身质量的18倍。In this study,hydrophobic cellulose nanofibril aerogel was prepared by sol-gel method and freeze drying method with TEMPO oxidized nanocellulose(CNF)as raw material,ammonium persulfate and anhydrous sodium sulfite as initiator,methyl trimethoxy silane(MTMS)as modifier and N,N′-methylene bis-acrylamide(MBA)as crosslinking agent.Silanol was generated by hydrolysis of methyl trimethoxy silane and hydrophobic modification was carried out through self-polymerization and hydroxy reaction on the surface of CNF to generate poly-siloxane bonds.MBA was cross-linked with hydroxyl,which increased the bonding strength between fibers.After discussion of the reaction conditions,it was found that when CNF was 10 g,the temperature was 55℃,pH was 8,the amount of MTMS was 3 mL,and the reaction time was more than 5 h,the aerogel with excellent performance,density less than 0.03 g/cm3,and porosity more than 98%could be obtained.FTIR and scanning electron microscope analysis confirmed the successful reaction between MTMS,MBA and CNF.The adsorption capacity of aerogel to waste oil could reach 18 times of its own mass,and the contact angle to water could reach more than 130°,showing a good hydrophobic and oil absorption performance.

关 键 词：纤维素纳米纤丝 气凝胶 甲基三甲氧基硅烷 N N-亚甲基双丙烯酰胺 疏水改性 

分 类 号：TS758[轻工技术与工程—制浆造纸工程]