Reactive sintering of B4C-TaB2 ceramics via carbide boronizing:Reaction process, microstructure and mechanical properties  

作　　者：Junfeng Gu Ji Zou Peiyan Ma Hao Wang Jinyong Zhang Weimin Wang Zhengyi Fu 

机构地区：[1]State Key Laboratory of Advanced Technology for Materials Synthesis and Processing.Wuhan University of Technology,Wuhan,430070,China [2]School of Metallurgy and Materials,University of Birmingham,B152TT,Birmingham,UK [3]School of Chemistry,Chemical Engineering and Life Science,Wuhan University of Technology,Wuhan.430070,China

出　　处：《Journal of Materials Science & Technology》2019年第12期2840-2850,共11页材料科学技术（英文版）

基　　金：financially supported by the National Natural Science Foundation of China (Nos. 51521001 and 51832003)

摘　　要：Carbide boronizing is a promising approach to obtain fine grained boron carbide based ceramics with improved mechanical properties. In this work, reaction process, microstructural characteristics and mechanical properties of BxC-TaB2(x = 3.7, 4.9, 7.1) ceramics were comprehensively investigated via this method. Dense BxC-TaB2 ceramics with refined microstructure were obtained from submicro tantalum carbide and boron powder mixtures at 1800℃/50 MPa/5 min by spark plasma sintering. The stoichiometry of boron carbide was determined from lattice parameters and Raman shift. It was found that uniformly distributed TaB2 grains in the BxC matrix is favor of the densification process and restricting grain growth.Besides, planar defects with high density were observed from the as-formed B7.1 C grains and transient stress was considered to contribute to the densification involved with plastic deformation. Microstructural observations indicate the dissolution of oxygen in the TaB2 lattice and most of the B7.1 C/TaB2 phase boundaries were clean. Owing to the highly faulted structure and finer grain size, as-obtained BxC-TaB2 ceramics exhibit high Vickers hardness(33.3–34.4 GPa at 9.8 N) and relatively high flexural strength ranging from 440 to 502 MPa.Carbide boronizing is a promising approach to obtain fine grained boron carbide based ceramics with improved mechanical properties. In this work, reaction process, microstructural characteristics and mechanical properties of BxC-TaB2（x = 3.7, 4.9, 7.1） ceramics were comprehensively investigated via this method. Dense BxC-TaB2 ceramics with refined microstructure were obtained from submicro tantalum carbide and boron powder mixtures at 1800?C/50 MPa/5 min by spark plasma sintering. The stoichiometry of boron carbide was determined from lattice parameters and Raman shift. It was found that uniformly distributed TaB2 grains in the BxC matrix is favor of the densification process and restricting grain growth.Besides, planar defects with high density were observed from the as-formed B7.1 C grains and transient stress was considered to contribute to the densification involved with plastic deformation. Microstructural observations indicate the dissolution of oxygen in the TaB2 lattice and most of the B7.1 C/TaB2 phase boundaries were clean. Owing to the highly faulted structure and finer grain size, as-obtained BxC-TaB2 ceramics exhibit high Vickers hardness（33.3–34.4 GPa at 9.8 N） and relatively high flexural strength ranging from 440 to 502 MPa.

关 键 词：Boron carbide Reaction sintering DENSIFICATION Microstructure Mechanical properties 

分 类 号：TQ174.75[化学工程—陶瓷工业]