氧化石墨烯协同二硫代焦磷酸酯阻燃粘胶纤维的制备及其性能  

Preparation and properties of flame-retardant viscose fiber/dithiopyrophosphate incorporated with graphene oxide

作　　者：马君志 王冬 付少海[1] MA Junzhi;WANG Dong;FU Shaohai(Key Laboratory of Eco-Textiles (Jiangnan University), Ministry of Education, Wuxi, Jiangsu 214122, China;CHTC Helon (Weifang) New Materials Co., Ltd., Weifang, Shandong 261100, China)

机构地区：[1]生态纺织教育部重点实验室(江南大学),江苏无锡214122 [2]恒天海龙(潍坊)新材料有限责任公司,山东潍坊261100

出　　处：《纺织学报》2020年第3期15-19,38,共6页Journal of Textile Research

基　　金：国家重点研发计划项目(2017YFB0309004);江苏省自然科学基金项目(BK20190613)。

摘　　要：为提高粘胶/二硫代焦磷酸酯(VF/DDPS)纤维的阻燃及力学性能,以氧化石墨烯(GO)作为协同阻燃剂添加到VF/DDPS基体中,通过湿法纺丝工艺制得VF/DDPS/GO复合纤维。借助热重分析仪、极限氧指数仪、微型量热仪和单丝强力仪研究GO对VF/DDPS复合纤维热性能、阻燃性能和力学性能的影响。结果表明:与VF/DDPS纤维相比,当GO质量分数为2.0%时,VF/DDPS/GO复合纤维的残炭量从20.0%增加到29.7%,极限氧指数从27.8%升高到29.1%,热释放速率峰值从141.5 W/g降低到99.4 W/g,干、湿断裂强度分别从2.08、0.96 cN/dtex增加到2.20、1.17 cN/dtex;GO的添加可提高VF/DDPS炭渣的石墨化程度和致密度,增强炭渣的热质阻隔作用。To improve the flame-retardant and mechanical properties of viscose fiber/bisneopentyl glycol dithiopyrophosphate(VF/DDPS),graphene oxide(GO)was incorporated into VF/DDPS matrix as synergistic flame retardant to prepare VF/DDPS/GO composite fiber through wetting spinning.Using thermogravimetry,limiting oxygen index tester,microscale combustion calorimeter and single fiber tensile tester as performance indices,the effect of GO on the thermal,flame-retardant and mechanical properties of VF/DDPS composite fiber were studied.The results show that compared to VF/DDPS,when incorporating 2.0%GO,the char residues of VF/DDPS/GO composite fiber increases from 20.0%to 29.7%,limiting oxygen index rises from 27.8%to 29.1%,peak heat release rate decreases from 141.5 to 99.4 W/g and dry/wet breaking strength increases from 2.08,0.96 cN/dtex to 2.20,1.17 cN/dtex.It is concluded that GO could enhance the graphitic degree and compactness of char residues,which strengthens the barrier action of heat and mass.

关 键 词：粘胶纤维 氧化石墨烯 二硫代焦磷酸酯 阻燃纤维 阻燃剂 

分 类 号：TS102.6[轻工技术与工程—纺织工程]