Advances in Enantioselective Construction of Trifluoromethoxylated Stereogenic Carbon Centers  

作　　者：Xiaohuan Jiang Pingping Tang 

机构地区：[1]State Key Laboratory and Institute of Elemento-Organic Chemistry,College of Chemistry,Nankai University,Tianjin 300071,China

出　　处：《Chinese Journal of Chemistry》2020年第1期101-102,共2页中国化学（英文版）

摘　　要：In recent years,the trifluoromethoxy(OCF3)functional group has received extensive attention in phar-maceuticals,agrochemicals and material sciences.However,the methods for the enantioselective syn-thesis of trifluoromethoxylated stereogenic carbon centers are rare owing to the nature of easy decom-position of OCF3 anion and limited OCF3 reagent.And the asymmetric trifluoromethoxylation will be a hot research topic in near future due to the unique biological properties of a single isomer.This article mainly focuses on the recent advances in the enantioselectiveconstruction of trifluoromethoxylated stereogenic carbon centers.

关 键 词：methoxyl REAGENT CENTERS 

分 类 号：O62[理学—有机化学]