蒽基修饰的新型铂基大环化合物的合成  

Synthesis of Platinum-based Macrocyclic Compound Containing Anthracenes-modified

作　　者：郭大政 李登科 刘雨 李贤英[2] 金武松[1] 张灯青[1] GUO Da-zheng;LI Deng-ke;LIU Yu;LI Xian-ying;JIN Wu-song;ZHANG Deng-qing(College of Chemistry,Chemical Engineering and Biotechnology,Donghua University,Shanghai 201620,China;College of Environmental Science and Engineering,Donghua University,Shanghai 201620,China)

机构地区：[1]东华大学化学化工与生物工程学院,上海201620 [2]东华大学环境科学与工程学院,上海201620

出　　处：《合成化学》2020年第2期113-117,共5页Chinese Journal of Synthetic Chemistry

基　　金：上海市自然基金资助项目(18ZR1400900)。

摘　　要：以3,5-二溴苯甲醚为起始原料,通过Suzuki偶联反应制得3,5-二吡啶苯甲醚(3);3经三溴化硼脱保护得到3,5-二吡啶苯酚(4);4进一步发生亲核取代反应得到化合物5;化合物6与5组装得到新型铂基超分子大环,其结构经1H NMR和31P NMR表征。3,5-Dipyridine anisole(3) was successfully prepared from 3,5-dibromoanisole by Suzuki-coupling reaction. 3,5-Dipyridylphenol(4) was obtained through deprotection of 3, which was further treated with nucleophilic substitution to give new compound 5. Compound 6 and 5 were coupled through coordination-driven self-assembling to give an unreported organometallic macrocyclic compound. The structure was characterized by 1H NMR and 31P NMR.

关 键 词：蒽 配位键导向 自组装 铂基大环 偶联反应 合成 超分子 

分 类 号：O625.15[理学—有机化学] O626[理学—化学]