新型双氨类发光材料的合成与性能研究  

Synthesis and Property of A Novel Diamine Luminescent Material

作　　者：李瑞 杨振强[1] 马欣 化林[1] 陈辉[1] 杨瑞娜[1] LI Rui;YANG Zhen-qiang;MA Xin;HUA Lin;CHEN Hui;YANG Rui-na(Henan Academy of Sciences Institute of Chemistry Co.,Ltd.,Zhengzhou 450002,China)

机构地区：[1]河南省科学院化学研究所有限公司,河南郑州450002

出　　处：《合成化学》2020年第2期133-137,共5页Chinese Journal of Synthetic Chemistry

基　　金：国家自然科学基金资助项目(21502045);河南省科技创新人才计划项目(174100510018)。

摘　　要：以3-溴-9,9-二甲基芴为原料,通过Buchwald-Hartwig偶联反应合成了一种新化合物N,N′-二(联苯-4-基)-N,N′-二(9,9-二甲基芴-3-基)-9-苯基咔唑-2,7-二胺(2),其结构和性能经FL, UV-Vis,~1H NMR, GC-MS(EI),元素分析和TG-DSC表征。结果表明:2具有较好的热稳定性和较高的玻璃化温度,失重5%的温度为452℃,玻璃化温度为176℃;在425 nm波长激发下,2在445 nm处发出较强荧光(蓝光)。A new compound N,N′-bis(biphenyl-4-yl)-N,N′-bis(9,9-dimethylfluoren-3-yl)-9-phenylcarbazole-2,7-diamine(2) was synthesized from 3-bromo-9,9-dimethylfluorene through Buchwald-Hartwig coupling reaction. The structure and performance of 2 were characterized by FL, UV-Vis, ~1H NMR, GC-MS(EI), elemental analysis and TG-DSC. The results showed that 2 had high thermal stability which 5% weight loss temperature was 452 ℃ and glass transition temperature was 176 ℃. 2 emitted strong fluorescence at 445 nm belongs at the PL excitation wavelength 425 nm.

关 键 词：咔唑衍生物 合成 性能 空穴传输材料 荧光 

分 类 号：O625.46[理学—有机化学]