Synthesis and Electronic Structure of Triazasubporphyrin with Peripherally Low Symmetric Push-pull Substitutions  

作　　者：FAN Yu-Xuan YUAN Tai-Yan LV Qing-Yang LI Min-Zhi ZHU Wei-Hua LIANG Xu 樊宇轩;袁太艳;吕庆洋;李敏智;朱卫华;梁旭(School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang 212013,China)

机构地区：[1]School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang 212013,China

出　　处：《Chinese Journal of Structural Chemistry》2020年第1期36-40,2,共6页结构化学（英文）

基　　金：Financially supported by the National Natural Science Foundation of China(No.21701058);the Natural Science Foundation of Jiangsu province(No.BK20160499);the State Key Laboratory of Coordination Chemistry(SKLCC1817);the Key Laboratory of Functional Inorganic Material Chemistry(Heilongjiang University)of Ministry of Education,the China post-doc foundation(No.2018M642183);the Lanzhou Entrepreneurial and Innovative Talents Project(2018-RC-105);the Jiangsu University(No.17JDG035)。

摘　　要：Peripherally low symmetric substitution with electron-donating(EDG)and electron-withdrawing(EWG)substituents caused the rational modulation of geometric structure and even the electronic structure of triazasubporphyrin,the smallest 14πconjugated aza-porphyrinoids.Both structural characterization and spectroscopic investigation were discussed to provide an in-depth understanding of the relationship between peripheral push-pull substituents and SubPz core.

关 键 词：triazasubporphyrin PUSH-PULL effect ELECTRONIC structure seterochemistry 

分 类 号：O621.3[理学—有机化学]