两种季铵盐型离子液体钯配合物的合成  

Synthesis of Two Ionic Liquid Palladium Complexes with Quaternary Ammonium Salt

作　　者：籍向东 王宇 蔡亮亮 高建疆 JI Xiang-dong;WANG Yu;CAI Liang-liang;GAO Jian-jiang(Key Laboratory of Hexi Corridor Resources Utilization of Gansu,Hexi College,Zhangye 734000,China)

机构地区：[1]河西学院甘肃省河西走廊特色资源利用重点实验室,甘肃张掖734000

出　　处：《合成化学》2020年第3期234-238,共5页Chinese Journal of Synthetic Chemistry

基　　金：甘肃省科技计划资助项目(18JR3RG205);河西学院第八批大学生科技创新项目(2018-132)。

摘　　要：以苯甲酰肼和4-醛基吡啶为原料,经过缩合反应制备亚胺型化合物1,分别与苄氯和对二苄氯结合制备了两个新型的离子液体型亚胺配体2和3;配体2和3分别与醋酸钯反应得到新型离子液体型钯配合物4和离子液体型自组装钯配合物5,其结构经1H NMR,13C NMR,IR和HR-MS(ESI)确证。A novel imine compound 1 was synthesized by condensation reaction using benzoyl hydrazine and 4-pyridinecarboxaldehyde as the starting material.The ionic liquid type of imine compounds 2 and 3 were obtained by reaction of compound 1 with benzyl chloride and 1,4-bis(chloromethyl)benzene,respectively.The ionic liquid type of palladium complex 4 and self-assembled palladium complex 5 were synthesized by reaction of Pd(OAc)2 to compound 2 and 3,respectively.The structures were confirmed by 1H NMR,13C NMR,IR and HR-MS(ESI).

关 键 词：苯甲酰肼 吡啶 离子液体 钯配合物 缩合反应 合成 

分 类 号：O614.82[理学—无机化学] O626[理学—化学]