含 Sm 聚合物的制备及荧光性质  

PREPARATION AND FLUORESCENCE PROPERTIES OF Sm-CONTINING COPOLYMERS

作　　者：张其锦[1] 陈国栋[1] 汪月生 罗筱烈[1] 

机构地区：[1]中国科学技术大学

出　　处：《材料科学进展》1992年第5期435-439,共5页

基　　金：国家自然科学基金;2880202

摘　　要：用 Sm_2O_3制备了甲基丙烯酸钐和辛酸钐。通过添加或交联制得了含 Sm 的甲基丙烯酸和甲基丙烯酸甲酯共聚物。测定了 Sm 盐的元素分析、IR、TG、DTA 和它们在溶液中的荧光性质。研究了含 Sm聚合物的力学性能和荧光性质。Sm-containing copolymers of methyl methacrylate and methacrylic acid wereprepared using samarium octanoate[Sm(OCA)_3]as additive and samarium methacrylate[Sm(MAA)_3]as crosslinking agent,respectively.The study on fluorescence properties of thecopolymers showed that there are linear relationships between fluorescence intensity and Smcontents of both two solids.Other results proved that copolymer crosslinked through samariummethacrylate is of better thermal stability,longer extension at break and stronger fluorescenceintensity at the same Sm contents than copolymer blended with Sm(OCA)_3.

关 键 词：稀土 荧光材料 钐 

分 类 号：O634.3[理学—高分子化学]