柱[5]芳烃的构象和平面手性  

Conformation and Planar Chirality of Pillar[5]arenes

作　　者：邹广卿 杨勇[1] Zou Guangqing;Yang Yong(Department of Chemistry,Zhejiang Sci-Tech University,Hangzhou 310018,China)

机构地区：[1]浙江理工大学化学系,浙江杭州310018

出　　处：《广东化工》2020年第4期101-103,共3页Guangdong Chemical Industry

摘　　要：柱[5]芳烃由于桥连亚甲基的自由度和2-,5-位衍生化的特点而具有多种构象及平面手性。对柱[5]芳烃构象和平面手性的研究,有助于深入理解其主客体识别能力和选择性。本文综述了柱[5]芳烃的构象异构现象,详细阐述了固定构象的方法,及其平面手性的翻转与拆分,讨论了手性柱[5]芳烃在不对称催化和水分子通道等领域的应用前景。Due to their free rotation of phenylene units and substitution at the 2-and 5-positions, pillar[5]arenes have abundant conformations and planar chirality properties. Investigation of the conformation and planar chirality of pillar[5]arenes is essential to understand their host-guest recognition abilities and selectivities. In this review, we summarize the conformational stereoisomeric phenomenon and demonstrate the methods for fixing conformation, chirality inversion and resolution of enantiomers of pillar[5]arenes. The applications of chiral pillar[5]arenes such as asymmetric catalysts and water channels are discussed.

关 键 词：芳烃 构象异构 平面手性 主客体识别 机械互锁结构 

分 类 号：TQ[化学工程]