纳米氧化铜对磷酸盐胶黏剂耐水性能的影响  

Effect of Nano CuO on Water Resistance of Phosphate Adhesive

作　　者：刘子浩 王明超[1] 郭安然[1] 刘家臣[1,2] Liu Zihao;Wang Mingchao;Guo Anran;Liu Jiachen(Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education,Tianjin University,Tianjin 300072,China;Tianjin University(Qingdao)Marine Engineering Research Institute Co.,Ltd.,Qingdao 266200,China)

机构地区：[1]天津大学先进陶瓷与加工技术教育部重点实验室,天津300072 [2]天津大学(青岛)海洋工程研究院有限公司,山东青岛266200

出　　处：《稀有金属材料与工程》2020年第2期577-581,共5页Rare Metal Materials and Engineering

基　　金：智库基金-特种密封材料及其系列化研究(201707051001)。

摘　　要：以H3PO4和Al(OH)3为基体,纳米氧化铜为填料来制备磷酸盐无机胶黏剂。胶黏剂粘结的莫来石片,在人工海水中浸泡168 h后,测试其剪切强度,并以此强度为标准,来探究纳米氧化铜的加入对磷酸盐胶黏剂耐水性能的影响。研究结果表明,纳米氧化铜可以有效改善粘结剂的耐水性能,并且当加入量为基体的20%(质量分数,下同)时,经150℃处理的莫来石粘结片浸泡在人工海水中168 h的抗剪切强度最高,为7.13 MPa;莫来石粘结片经1300℃处理后,浸泡在人工海水的抗剪切强度最低,为2.31 MPa;发现经煅烧处理的纳米氧化铜相比未煅烧处理的氧化铜可以更好地提高粘结剂粘结强度。Phosphate adhesive were prepared using the H3PO4 and Al(OH)3 as the matrix and nano CuO as the inorganic fillers.The influence of nano CuO on the water resistance of phosphate adhesives was investigated by soaking mullite joints that were bonded by the adhesive in artificial seawater for 168 h.The results show that the nano CuO can improve the water resistance of the adhesive.The shear strength of mullite joint is 7.13 MPa which is the best strength after immersion in artificial seawater when the content of nano CuO in matrix is 20 wt%.The joint has good water resistance within the whole heat-treatment temperature range from 150℃ to 1300℃.The lowest shear strength is 2.31 MPa after heat-treatment at 1300℃ and immersion in artificial seawater.Compared with the nano CuO not heated at 900℃,the adhesive has better strength when the nano CuO heated at 900℃ is added into the adhesive.

关 键 词：磷酸盐 胶黏剂 耐水性 纳米氧化铜 

分 类 号：TQ433.5[化学工程]