芳基高价碘与烯丙基硅烷的[3,3]-重排反应研究进展  

Research progress on[3,3]-rearrangement reaction of aryl hypervalent iodine with allyl silane

作　　者：彭勃[1] 陈孟源 詹娅玲 董涛涛 PENG Bo;CHEN Mengyuan;ZHAN Yaling;DONG Taotao(College of Chemistry and Life Sciences,Zhejiang Normal University,Jinhua 321004,China)

机构地区：[1]浙江师范大学化学与生命科学学院,浙江金华321004

出　　处：《浙江师范大学学报（自然科学版）》2020年第2期176-183,共8页Journal of Zhejiang Normal University:Natural Sciences

基　　金：国家自然科学基金资助项目(21502171)。

摘　　要：芳基高价碘作为反应物参与的[3,3]-重排反应逐渐受到合成化学家的关注.通过查阅高价碘与烯丙基硅烷反应的文献资料,并且分析、归纳后,进一步对高价碘与烯丙基硅烷的[3,3]-重排反应进行了深入的探讨与研究.详细阐述了该反应的发展历程,以及该反应在各类杂环化合物合成中的应用.随着高价碘化学的发展,高价碘与烯丙基硅烷的[3,3]-重排反应模型对[3,3]-重排领域具有非常重要的指导意义.Aryl iodine reagents serving as coupling partner in[3,3]-rearrangement had received great attention from synthetic community.The[3,3]-rearrangement reaction of hypervalent iodine and allyl silane was further discussed and studied through analysis and conclusion of the relevant literatures related hypervalent iodine and allyl substitution reactions.The history of the reaction and the application of the reaction in the synthesis of various heterocyclic compounds were described in details.With the development of hypervalent iodine chemistry,the hypervalent iodine and allyl silane[3,3]-rearrangement reaction model was supposed to have very important guiding significance for the[3,3]-rearrangement field.

关 键 词：高价碘 烯丙基硅烷 [3 3]-重排 三氟化硼乙醚 烯丙基化 

分 类 号：O623.1[理学—有机化学] O625.2[理学—化学]