新型碳材料质子交换膜燃料电池Pt催化剂载体的研究进展  

Research Progress on Advanced Carbon Materials as Pt Support for Proton Exchange Membrane Fuel Cells

作　　者：罗燚 冯军宗[1] 冯坚[1] 姜勇刚[1] 李良军 LUO Yi;FENG Junzong;FENG Jian;JIANG Yonggang;LI Liangjun(Science and Technology on Advanced Ceramic Fibers and Composites Laboratory,College of Aerospace and Engineering,National University of Defense Technology,Changsha 410073,China)

机构地区：[1]国防科技大学空天科学学院,新型陶瓷纤维及其复合材料重点实验室,长沙410073

出　　处：《无机材料学报》2020年第4期407-415,共9页Journal of Inorganic Materials

基　　金：国家自然科学基金(51172279,51302317,51702360)。

摘　　要：质子交换膜燃料电池(PEMFC)具有能量转换效率高、功率密度大、室温启动快、噪音低和零污染等特点,有望减少二氧化碳排放量,缓解能源危机,在轨道交通、航空航天等领域具有广阔的应用前景。催化剂是PEMFC的关键材料, Pt催化氧还原反应活性和稳定性好,是广泛使用且很难被取代的电催化剂。然而Pt储量低、价格昂贵,导致PEMFC成本较高,使用Pt载体可减少PEMFC的Pt负载量,提高Pt利用率。碳材料具有成本低廉、比表面积大、孔结构丰富、电导率和表面性质可调等特性,是广泛应用的Pt载体。商用的炭黑载体对Pt的利用效率低,抗电化学腐蚀性较差。为了进一步提高PEMFC的性能和持续性,需要研发能够均匀负载Pt、高效利用Pt、抗电化学腐蚀性强且导电性好的碳载体,进而实现PEMFC的大规模应用。炭气凝胶、碳纳米管和石墨烯等新型碳载体具有独特的结构和性质,可以提高PEMFC性能和寿命,引起了研究者的广泛关注。本文对近年来PEMFC新型碳材料Pt载体的研究进展进行了较为详细的综述,并对其发展趋势作出了适当评论。Proton Exchange Membrane Fuel Cell(PEMFC) has the characteristics of high energy conversion efficiency, high power density, fast start-up at room temperature, low noise and zero pollution, which is expected to alleviate the energy crisis and reduce carbon dioxide emissions. It has broad application prospects in rail transit, aerospace and other fields. Catalyst is one of the key materials of PEMFC. Moreover, Pt catalysts are widely used and considered difficult to be replaced because of their good activity and stability in oxygen reduction reaction. Pt is expensive because of its limited storage. However, Pt loading could be significantly lessened by Pt support to improve PEMFC utilization. Carbon materials are widely used as Pt supports because of their low cost, high specific surface area, pore structure, adjustable conductivity and surface properties, but commercial carbon black supports have low utilization efficiency and poor electrochemical corrosion resistance for Pt. For realizing the large-scale application of PEMFC, it is necessary to develop new carbon supports which can uniformly disperse Pt, efficiently utilize Pt, be resistant to electrochemical corrosion, and have good conductivity, thus the performance and sustainability of PEMFC are improved. Carbon aerogels, carbon nanotubes, graphene and other new carbon supports with unique structures and properties, which are expected to improve PEMFC performance and life, have attracted the attention of many researchers. In this paper, the research progress on new carbon material as Pt support for PEMFC in recent years is reviewed systematically, and the development trend is also commented appropriately.

关 键 词：质子交换膜燃料电池 炭气凝胶 碳纳米管 石墨烯 综述 

分 类 号：TQ15[化学工程—电化学工业]