彩色纳米碳酸钙的研制  

Research and production of colorful nano-sized calcium carbonate

作　　者：颜鑫[1] Yan Xin(College of Chemical Engineering,Hunan Institute of Chemical Technology,Zhuzhou 412004,China)

机构地区：[1]湖南化工职业技术学院化学工程学院,湖南株洲412004

出　　处：《无机盐工业》2020年第5期53-55,89,共4页Inorganic Chemicals Industry

摘　　要：以纳米碳酸钙中试装置为平台,通过控温碳化、加热湿法染色、加热湿法改性和分散处理,制得了具有良好一次粒子形态的彩色纳米碳酸钙产品。激光粒度仪测试表明,彩色纳米碳酸钙产品的D50约为350 nm,具有粒度分布均匀、分布范围窄等特点。产品在空气中长期放置不氧化、不褪色,说明具有良好的化学稳定性。亲水性实验表明,彩色纳米碳酸钙产品在水中长时间放置、反复搅拌,仍然不沉降、不掉色,说明染色和活化都是牢固的。以酸性媒染蓝黑B染料和硬酯酸为例,分析了纳米碳酸钙的湿法染色和湿法活化机理,并且探讨了硬酯酸分子、染色剂分子和碳酸钙颗粒之间的化学交联作用。By means of temperature-controlled carbonization,heat-wet dyeing,heat-wet modification and dispersing treatment,the colorful nano-sized calcium carbonate products with good primary particle morphology were prepared on the platform of nano-sized calcium carbonate pilot plant.The laser granulometer test showed that the D50 of colorful nano-sized calcium carbonate products was about 350 nm,with uniform particle size distribution and narrow distribution range.Products placed in the air for a long time without oxidation,color fading,indicating a good chemical stability.The hydrophilic test showed that the colorful nano-sized calcium carbonate products do not settle and lose color after being placed in water for a long time and stirred repeatedly,indicating that the dyeing and activation were stable.Taking acid mordant blue black B dye and stearic acid as examples,the mechanism of wet dyeing and wet activation of nano-sized calcium carbonate was analyzed,and the chemical crosslinking between the molecules of stearic acid,dye agent and calcium carbonate particles was discussed.

关 键 词：彩色纳米碳酸钙 湿法染色 湿法活化 染色机理 

分 类 号：TQ132.32[化学工程—无机化工]