卤素原子的引入对二苯甲基自由基光稳定性、光物理性质及电致发光器件性能的影响  

Effects of Introducing Halogen Atoms to Biphenylmethyl Radical on Photostability,Photophysical and Electroluminescent Properties

作　　者：吴春晓 艾心 陈英鑫 崔志远 李峰[1] WU Chunxiao;AI Xin;CHEN Yingxin;CUI Zhiyuan;LI Feng(State Key Laboratory of Supramolecular Structure and Materials,College of Chemistry,Jilin University,Changchun 130012,China)

机构地区：[1]吉林大学化学学院,超分子结构与材料国家重点实验室,长春130012

出　　处：《高等学校化学学报》2020年第5期972-980,共9页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:51925303,51673080,91833304)资助.

摘　　要：通过在\%N\%-咔唑基-二(2,4,6-三氯苯)甲基自由基(CzBTM)的咔唑基团的3和6位引入卤素原子,合成了3个新的自由基分子(3,6-二氟-N-咔唑基)二(2,4,6-三氯苯)甲基自由基(F 2CzBTM)、(3,6-二氯-N-咔唑基)二(2,4,6-三氯苯)甲基自由基(Cl 2CzBTM)及(3,6-二溴-N-咔唑基)二(2,4,6-三氯苯)甲基自由基(Br 2CzTM).通过对比3个自由基分子与CzBTM的理论计算结果、电化学性质、光物理性质以及光稳定性,发现对于电子给-受体型的发光自由基,其光物理性质是外围取代基团的电负性和分子空间构型共同作用的结果.Cl 2CzBTM和Br 2CzTM具有较高的光致发光荧光量子效率,而F 2CzBTM在光照下具有最长的光致发光半衰期.与以CzBTM为发光层制备的电致发光器件相比,以Cl 2CzBTM和Br 2CzTM为发光层制备的有机电致发光器件的光谱均发生了蓝移,器件的最大外量子效率均有所提高,分别是其1.8倍和2.5倍.Based on(N-carbazolyl)bis(2,4,6-trichlorophenyl)methyl(CzBTM),three new radicals,(3,6-difluoro-N-carbazoly)bis(2,4,6-trichlorophenyl)methyl(F 2CzBTM),(3,6-dichloro-N-carbazoly)bis(2,4,6-trichlorophenyl)methyl(Cl 2CzBTM)and(3,6-dibromo-N-carbazoly)bis(2,4,6-trichlorophenyl)methyl(Br 2CzBTM),were synthesized.By introducing the halogen atoms(F,Cl,Br)to the carbazole moiety,the electrochemical properties,theoretical calculation results,photophysical properties as well as photostability of the new radicals change obviously comparing with CzBTM.Cl 2CzBTM and Br 2CzBTM display higher photoluminescence quantum yield and F 2CzBTM exhibits the highest stability under a UV pulse laser irradiation.The organic light-emitting didoes(OLEDs)using Cl 2CzBTM and Br 2CzBTM as emitters were fabricated and the electroluminescence spectra of them are blue-shifted comparing with that of CzBTM.The maximum external quantum yield(EQE max)of the devices based on Cl 2CzBTM and Br 2CzBTM are enhanced,which are 1.8 and 2.5 times that of CzBTM-based device,respectively.

关 键 词：二苯甲基自由基 光稳定性 双线态激子 有机电致发光器件 

分 类 号：O644[理学—物理化学]