具有染料选择性吸附的杂多酸季铵盐制备与性能研究  

Fabrication and selectivity adsorption ofanionicdyes onpolyoxometalate hybrids

作　　者：汤惠睫 韩哲 俞天寿 张明 金红晓[1] 葛洪良[1] 王新庆[1] 金顶峰[1] TANG Huijie;HAN Zhe;YU Tianshou;XU Lingliang;ZHANG Ming;JIN Hongxiao;GE Hongliang;WANG Xinqing;JIN Dingfeng(College of Materials and Chemistry,China Jiliang University,Hangzhou 310018,China;College of Quality and Safety Engineering,China Jiliang University,Hangzhou 310018,China)

机构地区：[1]中国计量大学材料与化学学院,浙江杭州310018 [2]中国计量大学质量与安全工程学院,浙江杭州310018

出　　处：《中国计量大学学报》2020年第1期65-70,共6页Journal of China University of Metrology

基　　金：浙江省自然科学基金项目(No.LY16B030006)。

摘　　要：目的:制备磷钼钒杂多酸季铵盐,并且在模拟废水中对亚甲基蓝和甲基橙染料的吸附性能进行探索。方法:采用多种不同比的钼酸钠、磷酸氢二钠、偏钒酸钠和四丁基溴化铵的溶液,通过红外光谱、XRD、氮气吸脱附、SEM等对杂多酸季铵盐进行表征和结构分析。结果:制备得三种磷钼钒杂多酸季铵盐。结论:三种杂多酸季铵盐(C 16 H 36 BrN-PMo 5V 10(PMo 5V 10),C 16 H 36 BrN-PMo 9V 3.2(PMo 9V 3.2)和C 16 H 36 BrN-PMo 11 V 1(PMo 11 V 1))对亚甲基蓝的吸附量分别为19.3268、117.3026和14.4877 mg·g-1,PMo 9V 3.2具有优秀的亚甲基蓝选择性吸附效果。Aims:To prepare quaternary ammonium salts of phosphorus,molybdenum and vanadium heteropoly acids in this paper,and explore the adsorption properties of methylene blue and methyl orange dyes in simulated waste water.Methods:Various solutions of sodium molybdate,disodium hydrogen phosphate,sodium metavanadate,and tetrabutylammonium bromide were used.The heteropoly acid season was determined by infrared spectroscopy,XRD,nitrogen adsorption and desorption,and SEM.Characterization and structural analysis of ammonium salts.Results:Three quaternary ammonium salts of phosphorus,molybdenum and vanadium heteropoly acids were prepared.Conclusions:The adsorption amounts of three heteropoly acid quaternary ammonium salts(C 16 H 36 BrN-PMo 5V 10(PMo 5V 10),C 16 H 36 BrN-PMo 9V 3.2(PMo 9V 3.2),C 16 H 36 BrN-PMo 11 V 1(PMo 11 V 1))on methylene blue are 19.3268,117.3026,and 14.4877 mg·g-1,PMo 9V 3.2 has excellent methylene blue selective adsorption effect.

关 键 词：吸附 微结构 杂多酸季铵盐 阳离子染料 

分 类 号：O063[理学]