[Ni(phen)2·Co(phen)2·2Co(DPC)2·4H2O]·13H2O双金属配合物的合成及其晶体结构  

Synthesis and Crystal Structure of binary Coordination Polymer[Ni(phen)2·Co(phen)2·2Co(DPC)2·4H2O]·13H2O

作　　者：蔡幸然 徐芬[1] 孙立贤[1] 刘颖雅 韦思跃 张晨晨 吴怡 魏胜 程日光 管彦洵 李彬 Cai Xingran;Xu Fen;Sun Lixian;Liu Yingya;Wei Siyue;Zhang Chenchen;Wu Yi;Wei Sheng;Cheng Riguang;Guan Yanxun;Li Bin(Guangxi Key Laboratory of Information Materials&Guangxi Collaborative Innovation Centre of Structure and Property for New Energy and Materials,School of Material Science and Engineering,Guilin University of Electronic Technology,Guilin 541004;School of Chemical Engineering,Dalian University of Technology,Dalian 116023,China)

机构地区：[1]广西信息材料重点实验室,广西新能源新材料结构与性能协同创新中心,桂林电子科技大学材料科学与工程学院,广西桂林541004 [2]大连理工大学化工学院,辽宁大连116023

出　　处：《广东化工》2020年第8期11-13,4,共4页Guangdong Chemical Industry

基　　金：国家自然科学基金(51971068,5187011196 and 51671062);广西新能源材料结构与性能协同创新中心(2012GXNSFGA06002);广西科技计划(AD17195073,2017AD23029);广西创新驱动发展专项(AA17202030-1)的资助。

摘　　要：采用水热法成功合成了一种结构新颖的二维层状钴镍双金属配合物[Ni(phen)2·Co(phen)2·2Co(DPC)2·4H2O]·13H2O(phen=1,10-菲啰啉,DPC=2,6-吡啶二羧酸),采用单晶X射线衍射对其结构进行了表征。结果表明该配合物属于三斜晶系、P1空间群,其晶胞参数为:Mr=1922.98,a=10.0585(18)nm,b=14.684(3)nm,c=14.931(3)nm,α=74.078(6)°,β=78.399(6)°,γ=75.279(6)°,V=2030.5(7)nm^3,Z=1。An novel cobalt-nickel binary metal complex[Ni(phen)2·Co(phen)2·2Co(DPC)2·4H2O]·13H2O was successfully synthesized hydrothermally by using 2,6-pyridinedicarboxylic acid,phenanthroline,cobalt nitrate and nickel nitrate as the raw materials,ethanol and water as solvents.The structure of the complex was characterized by X-ray single crystal diffraction.According to the analysis of X-ray single crystal diffraction data,the crystal belongs to triclinic system,space group P1 with Mr=1922.98,a=10.0585(18)nm,b=14.684(3)nm,c=14.931(3)nm,α=74.078(6)°,β=78.399(6)°,γ=75.279(6)°,V=2030.5(7)nm^3,Z=1.

关 键 词：双金属配合物 1 10-菲啰啉 2 6-吡啶二羧酸 晶体结构 

分 类 号：O641.4[理学—物理化学]