玫瑰红RB催化纤维的制备及其在交叉脱氢偶联反应中的应用  

Preparation of Rose Bangel Catalytic Fiber and Its Application in Cross Dehydrogenation Coupling Reaction

作　　者：刘杨[1] 赵强强[2] 姜建堂[1] 沈一峰[1] LIU Yang;ZHAO Qiang-qiang;JIANG Jian-tang;SHEN Yi-feng(College of Textile Science and Engineering,Zhejiang University of Technology(International Silk College),Hangzhou 310018,Zhejiang China;College of Chemical Engineering and Bioengineering,Donghua University,Shanghai 201600,China)

机构地区：[1]浙江理工大学纺织科学与工程学院(国际丝绸学院),杭州310018 [2]东华大学化学化工与生物工程学院,上海201600

出　　处：《染料与染色》2020年第2期41-45,共5页Dyestuffs and Coloration

摘　　要：以聚丙烯腈纤维为载体,通过乙二胺接枝改性,有机光催化剂-玫瑰红RB吸附,制备了一种腈纶负载光催化纤维。在其催化N-苯基四氢异喹啉及其衍生物和硝基甲烷的交叉脱氢偶联反应中,反应温度85℃,乙二胺用量60 mL,水用量100 mL,反应时间240 min,氨基接枝量1.61 mol%时,对RB染料的吸附量可达9.2%,收率均在81%以上,并在8次循环反应后仍然保持良好的稳定性和催化活性。A polyacrylonitrile-loaded photocatalytic fiber was prepared by grafting with ethylene diamine and adsorbing organic photocatalyst-Rose Bangel.In the cross-dehydro coupling reaction of N-phenyltetrahydroisoquinoline and its derivatives with nitromethane catalyzed by the fiber,the reaction temperature was 85℃,the amount of ethylenediamine was 60 mL,the amount of water was 100 mL,the reaction time was 240 min,and the amount of amino graft was 1.61 mol%,the adsorption amount of Rose Bangel can reach 9.2%,the yields were all above 81%,and the fiber still maintains good stability and catalytic activity after 8 cycles of reaction.

关 键 词：聚丙烯腈纤维 玫瑰红RB 催化 交叉脱氢偶联反应 

分 类 号：TQ610.499[化学工程—精细化工]