碱金属与碱土金属在煤炭热转化过程中的影响研究进展  

Research progress of the influence of alkali metals and alkaline earth metals on coal thermal chemical conversion

作　　者：梅艳钢 王志青[2] 高松平[1] 郑洪岩 张郃[1] 房倚天[2] MEI Yan-gang;WANG Zhi-qing;GAO Song-ping;ZHENG Hong-yan;ZHANG He;FANG Yi-tian(Taiyuan Institute of Technology,Taiyuan 030008,China;State Key Laboratory of Coal Conversion,Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan 030001,China)

机构地区：[1]太原工业学院,山西太原030008 [2]中国科学院山西煤炭化学研究所煤转化国家重点实验室,山西太原030001

出　　处：《燃料化学学报》2020年第4期385-394,I0001,共11页Journal of Fuel Chemistry and Technology

基　　金：国家自然科学基金青年基金(2190080794);山西省面上自然科学基金(201901D111321)资助。

摘　　要：对比阐述了AAEMs在煤炭热转化过程的影响与作用,论述了催化气化中炭结构转变、碱金属形态变化、催化剂失活等过程。AAEMs是催化气化的催化剂,是活性炭制备过程的造孔剂,也是高AAEMs煤利用过程的有害组分,同样也是煤灰提铝过程的焙烧活化剂。AAEMs与炭相互作用影响炭的表面结构,进而影响气化剂在炭表面的吸附与反应,而AAEMs与炭的相互作用也会影响AAEMs的挥发与释放,耦合催化气化与煤灰资源化利用可以有效降低催化剂回收成本。通过对比认识AAEMs在煤炭热转化中的影响与作用,以期为AAEMs作用下煤炭热转化过程提供新思路与方法。In order to comprehensively understand the catalytic gasification process, the influence of AAEMs during coal thermal chemical conversion was compared and explained. The main issues related to the catalytic gasification, such as the transformation of carbon structure, the conversion of alkali metals, and the deactivation of catalysts were discussed. AAEMs can be used as the catalysts for catalytic gasification, the pore making additives for activated carbon preparation, the activating agents in the process of aluminum extraction from coal ash by roasting, but also be regarded as hazard elements for high AAEMs coal utilization. The interaction between AAEMs and carbon can affect the surface structure of carbon to favor the adsorption and reaction of gasification agent on the carbon surface. As the same time, the volatilization and release of AAEMs can not be escaped, but the catalyst recovery can be effectively promoted by coupling the catalytic gasification and the coal ash resource utilization. By understanding the effect of AAEMs on coal thermal chemical conversion, we can propose novel ideas and innovation techniques for coal thermal chemical conversion with AAEMs addition.

关 键 词：催化气化 活性炭制备 AAEMs挥发 煤灰提铝 

分 类 号：TQ511[化学工程]