基于C3化合物合成丙烯酸甲酯的催化剂研究进展  

Advances in catalysts for synthesis of methyl acrylate from C3 compounds

作　　者：赵志远 荆涛[1] 田景芝[1] 赵云鹏[1] 娄丛强 王超[1] 赵春琦 ZHAO Zhi-yuan;JING Tao;TIAN Jing-zhi;ZHAO Yun-peng;LOU Cong-qiang;WANG Chao;ZHAO Chun-qi(School of Chemistry and Chemical Engineering,Qiqihar University,Qiqihar 161000,China)

机构地区：[1]齐齐哈尔大学化学与化学工程学院,黑龙江齐齐哈尔161000

出　　处：《现代化工》2020年第4期51-55,共5页Modern Chemical Industry

基　　金：齐齐哈尔大学研究生创新科研项目(YJSCX2019040)。

摘　　要：介绍了以C3为原料制丙烯酸甲酯的工艺路线,重点对醋酸甲酯和甲醛羟醛缩合合成丙烯酸甲酯的催化剂研究进展进行综述,认为此工艺有望替代石油路线成为下一个产业化模式;结合工业生产现状和气固相催化反应产率,对这种合成路线催化剂的下一步开发进行了展望。The process routes using C3 fractions to synthesize methyl acrylate are introduced,with focus on the research advances in catalysts for the synthesis of methyl acrylate through aldol condensation between methyl acetate and formaldehyde.Moreover,it is pointed out that this process is expected to become the next generation mode for industrial production of methyl acrylate instead of present petroleum routes.Based on the present industrial production situation and the yield of gas-solid catalytic reaction,the future development of the catalyst for this route is prospected.

关 键 词：丙烯酸甲酯 醋酸甲酯 羟醛缩合 气固相催化 

分 类 号：TQ22[化学工程—有机化工]