新型含二茂铁有机配合物的合成及其电化学性质  

Synthesis and Electrochemical Properties of A Novel Organic Complex Containing Ferrocene

作　　者：肖文杰 曹海泳 林艳[1] 刘文琴[1] 万屏南[1] 崔汉峰[1] XIAO Wen-jie;CAO Hai-yong;LIN Yan;LIU Wen-qin;WAN Ping-nan;CUI Han-feng(College of Pharmacy,Jiangxi University of Traditional Chinese Medicine,Nanchang 330004,China)

机构地区：[1]江西中医药大学药学院,江西南昌330004

出　　处：《合成化学》2020年第4期341-345,共5页Chinese Journal of Synthetic Chemistry

基　　金：国家自然科学基金资助项目(81560625);江西省教育厅科技项目(160829,190668);江西省卫生厅中医药科技项目(2016B017);江西中医药大学研究生创新项目(JZYC18S05);江西省高等学校教学改革课题(JXJG-16-12-20)。

摘　　要：以二茂铁为起始原料,经氯汞化反应、溴代反应、Suzuki偶联反应、水解反应和取代反应等5步反应合成了一种新型的含二茂铁结构单元的有机配合物(7),其结构经1H NMR、13C NMR、IR和HR-MS(ESI-TOF)表征。电化学研究结果表明:化合物6的E1/2小于化合物7,具有较高的氧化还原活性。A novel organic complex(7)containing ferrocene structural units was synthesized from ferrocene as starting material by chloromeridation,bromination,Suzuki coupling,hydrolysis and substitution reactions.The structure was characterized by 1H NMR,13C NMR,IR and HRMS.The results of electrochemical studies show that the E1/2 ratio of compound 6 is lower than compound 7,indicating that compound 6 is easy to lose electrons and had higher redox activity.

关 键 词：二茂铁 SUZUKI偶联反应 合成 配合物 电化学性质 

分 类 号：O627.8[理学—有机化学] O657.1[理学—化学]