过渡金属催化sp^3C-H键活化构筑sp^3C-P键反应研究进展  

Recent Progress in Transition-Metal-Catalyzed sp3^C-H Activation for the sp^3C-P Bonds Construction

作　　者：全丽霞 何洪红 祝显虹 计从斌 周安西 戚丽 毛刘量 QUAN Lixia;HE Honghong;ZHU Xianhong;JI Congbin;ZHOU Anxi;QI Li;MAO Liuliang(School of Chemistry and Environmental Sciences,Shangrao Normal University,Shangrao Jiangxi 334001,China)

机构地区：[1]上饶师范学院化学与环境科学学院,江西上饶334001

出　　处：《上饶师范学院学报》2020年第3期36-44,共9页Journal of Shangrao Normal University

基　　金：江西省教育厅科技计划项目(GJJ180880);化学与环境科学学院校友资助研究项目(D0105-13);上饶师范学院校级课题(201601)。

摘　　要：含sp^3C-P键化合物是一类重要的化学原料和有机合成中间体。近年来,通过过渡金属催化sp^3C-H键活化反应来构筑sp^3C-P键受到了广泛关注并取得了显著的发展。根据不同的过渡金属催化剂进行分类,对近年来过渡金属催化sp^3C-H键活化构筑sp^3C-P键反应进行了综述,并对该研究领域的局限性和未来发展前景进行总结和展望。Compounds containing sp^3C-P bond are of great importantance as chemical raw materials and organic synthesitical intermediates.In recent years,the construction of sp^3C-P bond by transition metal catalyzed sp^3C-H bond activation attracted wide attention and made great progress.According to different transition metal catalysts,this review summarized the research progress on transition-metal-catalyzed sp^3C-H activation for the sp^3C-P bond construction,and the limitations of the research field and prospects for future development are presented.

关 键 词：过渡金属催化 sp 3碳-磷键 有机磷 脱氢氧化偶联反应 sp 3 C-H键活化 

分 类 号：O621.25[理学—有机化学]