Remote Chirality Transfer through Medium Cycle Formation/Intramolecular Hydride Transfer Cascade  

作　　者：Juan Chend Bo Liu 

机构地区：[1]Analytical&Testing Center,Sichuan University,Chengdu,Sichuan 610064,China [2]Key Laboratory of Green Chemistry&Technology of Ministry of Education,College of Chemistry,Sichuan University,Chengdu,Sichuan 610064,China

出　　处：《Chinese Journal of Chemistry》2020年第3期305-306,共2页中国化学（英文版）

摘　　要：Intramolecular hydride transfer has long been recognized as a powerful method to gen-erate new stereogenic centers induced by the existing stereogenic center(s).Synthetical-ly significant selectivities are usually obtained through 1,5-hydride transfer within six-membered ring.This mini-review focuses on a transannular hydride transfer generating up to three stereocenters simultaneously from a single stereogenic center through for-mation of medium rings,mostly eight-membered rings,in mild reaction conditions.The corresponding linear products with multiple stereocenters are potentially useful building blocks for synthesis of complex molecules including polyketide natural products.

关 键 词：HYDRIDE CENTERS transfer 

分 类 号：O62[理学—有机化学]