三聚氰胺基多元醇的合成及其在聚氨酯中的应用进展  

Progress on Synthesis of Melamine-based Polyols and Its Application in Polyurethane

作　　者：许邵帅 宋文生[1] 王俊锴 刘继纯[1] XU Shao-shuai;SONG Wen-sheng;WANG Jun-kai;LIU Ji-chun(School of Chemical Engineering&Pharmacy,Henan University of Science and Technology,Luoyang 471023,China)

机构地区：[1]河南科技大学化工与制药学院,河南洛阳471023

出　　处：《塑料科技》2020年第4期103-107,共5页Plastics Science and Technology

基　　金：国家自然科学基金河南省联合基金项目(U1704144)。

摘　　要：以三聚氰胺为主原料,综述了由其制备三聚氰胺基多元醇的方法,包括三聚氰胺经羟甲基化后再醚化、Mannich反应、三聚氰胺羟甲基化物作为起始剂由环氧化物开环聚合、三聚氰胺为起始剂由环氧化物开环聚合、氨基交换法以及其他方法,并介绍了三聚氰胺基多元醇在聚氨酯方面的应用。Several preparation methods of melamine-based polyols were reviewed with melamine as major material,such as hydroxymethylation of melamine followed by etherification,Mannich reaction,ring-opening polymerization of epoxides with hydroxymethylated melamine as a starter,ring-opening polymerization of epoxides with melamine as a direct starter,amino-exchange reaction and so on.Furthermore,the application of the above melamine-based polyols in polyurethane were also briefly introduced.

关 键 词：三聚氰胺 阻燃型多元醇 聚氨酯泡沫 应用 

分 类 号：TQ328.3[化学工程—合成树脂塑料工业]