氰根修饰的MOF结构的合成与性质研究  

Synthesis and Properties of Cyanide Modified MOF Structure

作　　者：王美佳 苏占华[1,2] 田云艳 王丹 宋瑶[1] Wang Meijia;Su Zhanhua;Tian Yunyan;Wang Dan;Song Yao(Harbin Normal University;Guangdong Institute of Petrochemical Technology)

机构地区：[1]哈尔滨师范大学 [2]广东石油化工学院

出　　处：《哈尔滨师范大学自然科学学报》2020年第2期44-49,共6页Natural Science Journal of Harbin Normal University

基　　金：广东石油化工学院科研基金人才引进项目(2019rc054)。

摘　　要：采取简单的一步水热合成方法,通过控制反应体系中的原料起始摩尔比、反应时间,合成了一例结构新颖的化合物[Cu(CN)2][Cu(4,4-bipy)],(4,4-bipy=4,4-Dipyridl).采用X-射线单晶衍射、元素分析、IR对合成化合物进行了结构表征.该化合物是由金属Cu与氰根作用连接和一个有机配合物构成.在紫外光照下,利用三种不同染料对化合物的光催化降解活性进行了研究.In this paper,a simple one-step hydrothermal synthesis method,by controlling the starting molar ratio of the raw materials in the reaction system and the reaction time,a case of a compound with a novel structure[Cu(CN)2][Cu(4,4-bipy)](4,4-bipy=4,4-Dipyridl)were synthesized.The structure of the synthesized compound was characterized by X-ray single crystal diffraction,elemental analysis,and IR.The results show that the compound is composed of metal Cu and cyanide,and an organic complex.Under ultraviolet light,three different dyes were used to study the photocatalytic degradation activity of the compounds.

关 键 词：MOF结构 晶体结构表征 光催化性质 

分 类 号：O61[理学—无机化学]