基于蒽衍生高迁移率发光材料的研究进展  

Recent Advances on High Mobility Emissive Anthracene-derived Organic Semiconductors

作　　者：谢子仪 刘单 张逸寒 刘情情 董焕丽[1,3] 胡文平 XIE Ziyi;LIU Dan;ZHANG Yihan;LIU Qingqing;DONG Huanli;HU Wenping(Beijing National Laboratory for Molecular Sciences,Key Laboratory of Organic Solids,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China;Tianjin Key Laboratory of Molecular Optoelectronic Sciences,Collaborative Innovation Center of Chemical Science and Engineering,School of Sciences,Tianjin University Tianjin,300072,China;University of Chinese Academy of Sciences,Beijing 100049,China;College of Chemistry,Xiangtan University,Xiangtan 411105,China)

机构地区：[1]中国科学院化学研究所,有机固体院重点实验室,北京分子科学国家研究中心,北京100190 [2]天津大学理学院,天津市分子光电科学重点实验室,天津大学协同创新中心,天津300072 [3]中国科学院大学,北京100049 [4]湘潭大学化学学院,湘潭411105

出　　处：《高等学校化学学报》2020年第6期1179-1193,共15页Chemical Journal of Chinese Universities

基　　金：国家重点研发计划“纳米科技”专项(批准号:2017YFA0204503);国家重点研发计划“战略性先进电子材料”专项(批准号:2016YFB0401100);国家自然科学基金(批准号:51725304,51733004,61890943,91833306);北京分子科学国家研究中心项目(批准号:BNLMS-CXXM-202012);中国科学院青年创新促进会项目资助.

摘　　要：高迁移率发光有机半导体材料是实现有机发光场效应晶体管(OLETs)的重要材料,但其设计合成面临巨大挑战.本文综合评述了近年来高迁移率发光材料,特别是基于蒽的高迁移率发光材料的研究进展,重点介绍了目前报道的20余种基于蒽的高迁移率发光有机半导体材料,包括分子的设计策略\,相关的光电性能及其在OLETs器件方面的应用研究,以便为进一步的相关研究提供有意义的指导和借鉴.本文还对该领域未来发展的挑战、发展方向及机遇进行了简单评述.High mobility emissive organic semiconductors are the important core materials for the realization of organic light-emitting transistors(OLETs).However,it remains a long-standing challenge for developing high mobility emissive organic semiconductors because of the different molecular design requirements as well as their molecular packing in solid state.Recently,significant advance has been achieved in the development of high mobility emissive organic semiconductors,especially for the anthracene-derived high mobility emissive materials,which would lead to the rapid development of this field.In this article,we first give a brief introduction for the significant progress in the whole field,and then focus on special development of high mobility emissive anthracene-derivatives(more than 20 types)along with their molecular structure design,molecular packing and optoelectronic properties as well as their applications in OLETs.Finally,the challenges,development directions and opportunities are discussed.Hopefully,this review would give a valuable guideline for the further research in this field.

关 键 词：蒽衍生物 高迁移率 强发光 有机发光场效应晶体管 

分 类 号：O625[理学—有机化学] O649[理学—化学]