铵浸钢渣熔融还原提铁制备微晶玻璃研究  

Study on Glass-ceramics Preparation through Melting Reduction of Steel Slag Leached by Ammonium Chloride

作　　者：孙靖婷 谭昭君 王江 韩笋 郭学益 童志博 SUN Jingting;TAN Zhaojun;WANG Jiang;HAN Sun;GUO Xueyi;TONG Zhibo(The Key Laboratory of Extraordinary Bond Engineering and Advanced Materials Technology, Yangtze Normal University, Chongqing 408000, China;School of Metallurgy and Environment, Central South University, Changsha 410012, China)

机构地区：[1]长江师范学院,超常配位键工程与新材料技术实验室,重庆408000 [2]中南大学冶金与环境学院,长沙410012

出　　处：《人工晶体学报》2020年第5期908-912,共5页Journal of Synthetic Crystals

基　　金：重庆市教育委员会科学技术研究项目(KJQN201801403);重庆市基础研究与前沿探索项目(cstc2018jcyjAX0457);重庆市涪陵区自然科学基金(FLKJ,2018BBA3058);长江师范学院自然科学基金(2017XJQN07)。

摘　　要：利用氯化铵浸出钢渣,可有效浸取Ca元素并就地固定CO2制备碳酸钙,浸出后的铵浸渣由于CaO含量的降低,无需加入大量的改质剂就能还原提铁并制备微晶玻璃。基于此,引入热力学计算,对铵浸钢渣提铁并制备微晶玻璃的可行性进行探究,初步结果表明铵浸钢渣与40wt%的SiO2混合后进行提铁,铁的还原率高达98.47%,且还原渣物相主要为透辉石;由还原渣制备得到的基础玻璃在800℃下核化1 h,960℃下晶化1 h,得到微晶玻璃,其主晶相为透辉石,并夹杂部分钙长石;基础玻璃析晶活化能为597.4 kJ/mol,晶体生长指数均小于3,为表面析晶。Calcium element can effectively be leached out and carbon dioxide can be sequestered on the spot to prepare commercial calcium carbonate through leaching of steel slag by ammonium chloride.Due to the decrease of CaO content in steel slag leached by ammonium,there is no need to use a lot of modification agent to reduce and extract iron and prepare glass-ceramics.Therefore,thermodynamic calculation was introduced to explore the feasibility of extracting iron from ammonium leaching steel slag and preparing glass-ceramics.The preliminary results shows that for the mixture of steel slag leached by ammonium chloride and 40wt%SiO2,the reduction rate of iron is as high as 98.47%,and the main phases of reducing residues is diopside;the main crystal phase of glass ceramics is diopside mixed up with some calcium feldspar by nucleation for 1 h at 800℃and crystallization for 1 h at 960℃;and the crystallization activation energy of base glass is 597.4 kJ/mol,and the crystal growth indexes are all less than three,indicating surface crystallization.

关 键 词：铵浸钢渣 铁还原 微晶玻璃 透辉石 

分 类 号：TQ171.7[化学工程—玻璃工业]