A Cu/Cinchona P,N-ligand system enabled general asymmetric C(sp^3)–C(sp) coupling  

作　　者：Xianwei Li Chao-Jun Li 

机构地区：[1]Department of Chemistry and FQRNT Center for Green Chemistry and Catalysis,McGill University,801 Sherbrooke St.W.,Montreal,Quebec H3A 0B8,Canada [2]School of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou 510006,China

出　　处：《Science China Chemistry》2020年第6期751-752,共2页中国科学（化学英文版）

摘　　要：Due to the special structural feature and versatile reactivity towards various types of transformations,alkynes have inspired continuous research interest for their generation,incorporation and application in organic synthesis,chemical biology and material science[1].Notably,since its invention in 1975,the Sonogashira reaction,which efficiently couples aryl halides with aryl or vinyl terminal alkynes via Pd(0)/Cu(I)synergistic catalysis.

关 键 词：A Cu/Cinchona P N-ligand system enabled general asymmetric C COUPLING 

分 类 号：O621.25[理学—有机化学]