长链烷氧基苯甲酰基硫脲的阴离子识别应用研究  

Anions recognition properties of long-chain alkoxy substituted benzoyl thiourea

作　　者：籍向东 汪燕飞 安平 尤兴梅 曹成[1] JI Xiang-dong;WANG Yan-fei;AN Ping;YOU Xing-mei;CAO Cheng(Key Laboratory of Hexi Corridor Resources Utilization of Gansu,College of Chemistry and Chemical Engineering,Hexi University,Zhangye 734000,China)

机构地区：[1]河西学院,甘肃省河西走廊特色资源利用重点实验室,化学化工学院,甘肃省张掖市734000

出　　处：《化学研究与应用》2020年第6期1007-1013,共7页Chemical Research and Application

基　　金：国家自然科学基金项目(21761011)资助;甘肃省科技计划资助项目(18JR3RG205)资助;甘肃省高校河西走廊特色资源利用重点实验室面上项目(XZ1601)资助;甘肃省高等学校科研项目(2018A-088)资助。

摘　　要：通过紫外光谱、核磁滴定等方式研究了两种长链烷氧基苯甲酰基硫脲对阴离子的识别性能。结果表明受体1可以对CN^-表现出良好的单一识别能力,F^-、AC^-和CN^-对受体2有明显UV-Vis响应,且在含15%H2O的DMSO溶液中,受体2可以单一识别CN^-。由于受体分子内电荷转移(ICT)的程度较大,故对阴离子均表现出裸眼识别性能。受体与阴离子之间的检出限范围为1.24×10^-7~1.87×10^-5M^-1,均表现出了较高的检测灵敏度。Recognition properties of two long-chain alkoxy substituted benzoyl thiourea with anions were studied by UV-vis studies,1H NMR titration and other analytical methods.The results of study showed that the receptor 1 has simplex recognition ability for CN^-,and F^-,AC^-and CN^-had obvious UV-Vis responses to receptor 2.Receptor 2 had simplex recognition ability for CN^-in 15%H2O-DMSO solution.Because the intramolecular charge transfer(ICT)of receptors were more obvious,and ability of naked-eye recognition for anions was shown.The detection limits of receptors for anions were calculated to be 1.24×10^-7~1.87×10^-5 M^-1,which indicated that the receptors were good sensors for detection of anions.

关 键 词：硫脲 检测试纸 阴离子识别 比色 

分 类 号：O623.8[理学—有机化学]