磷烯光催化分解水研究进展  

Progress on Phosphorene for Photocatalytic Water Splitting

作　　者：郑云 陈亦琳[1] 高碧芬[1] 林碧洲[1] ZHENG Yun;CHEN Yilin;GAO Bifen;LIN Bizhou(College of Materials Science and Engineering,Huaqiao University,Xiamen 361021,China;State Key Laboratory of Photocatalysis on Energy and Environment,College of Chemistry,Fuzhou University,Fuzhou 350116,China)

机构地区：[1]华侨大学材料科学与工程学院,厦门361021 [2]福州大学化学学院,能源与环境光催化国家重点实验室,福州350116

出　　处：《无机材料学报》2020年第6期647-653,共7页Journal of Inorganic Materials

基　　金：国家自然科学基金(21902051);福建省自然科学基金(2019J05090,2017J01014);福建省石墨烯复合材料研究中心(2017H2001);华侨大学科研基金(605-50Y17060);福州大学能源与环境光催化国家重点实验室开放课题(SKLPEE-201803)。

摘　　要：半导体光催化分解水被认为是解决全球能源短缺和环境污染问题的潜在途径之一。近年来,磷烯(BP)由于具有带隙可调、空穴迁移率高、吸收光谱宽等特性而在光催化分解水方面得到了广泛关注。本文综述了国内外近年来在磷烯光催化分解水领域所取得的重要研究进展,总结了磷烯基光催化剂的合成方法、表面修饰和异质结构构建等改性策略,阐述了磷烯基光催化剂的构–效关系和电荷转移机制,并展望了磷烯基光催化剂所面临的机遇和挑战,揭示了磷烯基材料在太阳能利用和转化方面的重要应用潜力。Semiconductor photocatalytic water splitting has been considered as a potential strategy to overcome global energy shortage and environmental pollution.In recent years,phosphorene(BP)attracted great attention in photocatalytic water splitting due to its adjustable band gap,high hole mobility and wide absorption spectrum.This review summarizes the recent significant advances on designing high-performance BP-based photocatalysts for water splitting.The synthetic methods and modification strategies(e.g.,surface modification and heterostructure design)of BP-based photocatalysts are described.Furthermore,in order to elucidate the structure-activity relationship of BP-based photocatalysts,the charge transfer mechanism is illustrated.Finally,the ongoing challenges and opportunities for the future development of BP-based photocatalysts in the exciting research area are highlighted.

关 键 词：磷烯 光催化 分解水 二维材料 综述 

分 类 号：O643[理学—物理化学]