结构化5A分子筛吸附床结构及工艺参数对N2/H2吸附性能的影响  

Effect of structured 5A molecular sieve adsorption bed structure and process parameters on N2/H2 adsorption performance

作　　者：王鹏 刘京雷[1] 张胜中[2] 范得权 张英[2] 徐宏[1] WANG Peng;LIU Jinglei;ZHANG Shengzhong;FAN Dequan;ZHANG Ying;XU Hong(State Key Laboratory of Chemical Engineering,School of Mechanical and Power Engineering,East China University of Science and Technology,Shanghai 200237,China;China Petrochemical(Dalian)Petrochemical Research Institute,Dalian 116050,Liaoning,China)

机构地区：[1]华东理工大学机械与动力工程学院,化学工程国家重点实验室,上海200237 [2]中国石化大连石油化工研究院,辽宁大连116050

出　　处：《化工学报》2020年第7期3114-3122,共9页CIESC Journal

基　　金：中石化科技开发资助项目(117018-4)。

摘　　要：利用吸附等温线获得动力学参数,建立了CFD模型,模拟了氢气/氮气在结构化5A分子筛吸附床中的吸附过程,研究了吸附剂层片间距、吸附剂厚度等结构参数和吸附压力、进气流量等工艺参数对混合气吸附效果的影响。结果表明:减小层片间距和吸附剂厚度可显著提高传质系数和床层利用率。增大吸附压力可提高床层利用率,但会减小传质系数。进气流量对传质系数的影响不明显,但当流量较大时,吸附容量和床层利用率均呈减小趋势。结构化5A分子筛吸附剂吸附性能良好。The kinetic parameters were obtained by adsorption isotherm,and the CFD model was established to simulate the adsorption process of hydrogen/nitrogen in the structured 5A molecular sieve adsorption bed.The effects of structural parameters such as the adsorbent sheet spacing and thickness and process parameters such as adsorption pressure and volume flow rate on the adsorption performance to the mixed gas were discussed.The results show that reducing sheet spacing and thickness are beneficial to the mass transfer coefficient and bed saturation degree.Increasing the adsorption pressure can improve the bed saturation degree,but will reduce the mass transfer coefficient.The effect of the flow rate on mass transfer coefficient is not obvious,but when the flow rate is high,both the adsorption capacity and the bed saturation degree decrease.The structured 5A molecular sieve adsorbent has good adsoption performance.

关 键 词：结构化5A分子筛 吸附性能 氢气提纯 动力学模型 

分 类 号：TQ028.1[化学工程]