含[M′(CN)2]-桥连配体的Fe^Ⅱ霍夫曼类自旋交叉配合物  

Fe^Ⅱ Hofmann-like Spin Crossover Complexes with[M′(CN)2]-Bridging Ligand

作　　者：李金燕 侯得健 LI Jin-yan;HOU De-jian(School of Chemical and Environmental Engineering,Hanshan Normal University,Guangdong Chaozhou 521041,China)

机构地区：[1]韩山师范学院化学与环境工程学院,广东潮州521041

出　　处：《广州化工》2020年第12期45-47,共3页GuangZhou Chemical Industry

基　　金：国家自然科学基金青年科学基金项目(No:21701066);广东省基础与应用基础研究基金自然科学基金项目(面上项目)(No:2019A1515011359)。

摘　　要：自旋交叉配合物由于在显示器、分子开关、存储器、传感器等先进材料中有潜在的应用而受到研究者们的关注。Fe^Ⅱ霍夫曼类自旋交叉配合物通常具有结构稳定,表现出热致变色现象等特点,是研究自旋交叉性质的典型体系之一。在此对含[M′(CN)2]-(M′=Ag^I,Au^I,Cu^I)阴离子桥连配体的FeII霍夫曼类自旋交叉配合物进行总结,为后续的研究提供参考。Spin crossover complexes have attracted the attention of researchers because of their potential applications in advanced material of displays,molecular switches,storage and sensors.Fe^ⅡHofmann-like spin crossover complexes always have stable structures and exhibit thermochromic phenomenon.As a result,this type of complexes has become one of the typical systems for investigating spin crossover.Herein,Fe^Ⅱ Hofmann-like spin crossover complexes with[M′(CN)2]-(M′=Ag^I,Au^I,Cu^I)anion bridging ligand were summarized to provide a reference for subsequent studies.

关 键 词：自旋交叉 霍夫曼 二价铁 

分 类 号：O646.8[理学—物理化学]