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作 者:Cai Xinheng Long Jun Dong Ming Wang Wei Hou Huandi Tian Songbai
机构地区:[1]SINOPEC Research Institute of Petroleum Processing,Beijing 100083
出 处:《China Petroleum Processing & Petrochemical Technology》2020年第2期10-20,共11页中国炼油与石油化工(英文版)
摘 要:Asphaltenes generally exist in the form of molecular aggregates in crude oil or in petroleum residues,and asphaltene aggregates can usually cause serious problems to oil exploitation,transportation,and processing.Achieving deaggregation and separation of asphaltene aggregates is a premise and basis for molecular characterization and processing of heavy oils.Aiming at the intermolecular interactions in asphaltene molecular aggregates,it has proposed and summarized that aspahltene aggregates can be subject to deaggregation by means of five approaches,including solvent diluting,removing active sites,moderate heating,ultrasonication and on-line molecular collision.Moreover,asphaltenes can be further separated to narrow fractions for molecular-level research based on polarity difference,molecular size difference,acid-base properties,and reactivity difference.
关 键 词:ASPHALTENE MOLECULAR AGGREGATES DEAGGREGATION SEPARATION
分 类 号:TE626.86[石油与天然气工程—油气加工工程]
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