Numerical investigation of complex chemistry performing in Ptcatalyzed oxidative dehydrogenation of ethane fixed-bed reactors  

作　　者：Zhongfeng Geng Hao Deng Yonghui Li Minhua Zhang 

机构地区：[1]Key Laboratory for Green Chemical Technology of Ministry of Education.R&D Center for Petrochemical Technology,Tianjin University,Tianjin 300072,China [2]Collaborative Innovation Center of Chemical Science and Engineering,Tianjin 300072,China

出　　处：《Chinese Journal of Chemical Engineering》2020年第3期793-807,共15页中国化学工程学报（英文版）

摘　　要：Ethylene is one of the most important basic chemicals in the modern chemical industry.Thermal or catalytic cracking of hydrocarbons is the main industrial technologies nowadays,which suffer from equilibriumlimitation and rapid coke formation.The oxidative dehydrogenation of ethane(ODHE)is considered to be a promising alternative process since it overcomes equilibrium-limitations,avoids catalyst deactivation by coke formation,and decreases the number of side reactions.In this study,particle-resolved 2 D CFD simulations of fixed-beds filled with eggshell catalysts coupled with micro-kinetics of Pt-catalyzed ODHE were performed to understand the effect of operation conditions and catalyst properties on ethylene selectivity.The catalyst bed was created by discrete element method(DEM)and the central longitudinal section of the reactor tube was defined as the 2 D simulation region.Both of the homogeneous and catalytic heterogeneous chemical reactions were described by detailed micro-kinetics within the particle-resolved CFD simulation.At first,the established model of monolith reactors was verified by comparing the simulated results with experimental results reported in literature.Then,the effects of operation conditions and catalyst concentration on the ethylene selectivity in randomly packed beds were explored.The specific variation of certain operation conditions including inlet flow rate,inlet temperature,pressure,inlet C2 H6/O2 ratio and N2 dilution ratio can effectively increase ethylene selectivity.And the reduction of ratio of catalytic active area to geometric area Fcat/georepresenting catalyst properties from 140 to 30 increases the selectivity from 42.2%to 59.3%.This research can provide reference for the industrialization of ODHE process in the future.

关 键 词：ETHANE ETHYLENE Oxidative dehydrogenation SELECTIVITY CFD FIXED-BED 

分 类 号：TQ221.211[化学工程—有机化工]