Fused multifunctionalized bridge aromatic hydrocarbons from in situ-generated arynes and anthracene derivatives  

作　　者：Baohua Liu Qiong Hu Feihu Yang Xiaojie Zheng Yimin Hu 

机构地区：[1]Key Laboratory of Functional Molecular Solids,Ministry of Education,Anhui Laboratory of Molecule-Based Materials,State Laboratory Cultivation Base,College of Chemistry and Materials Science,Anhui Normal University,Wuhu 241002,China

出　　处：《Chinese Chemical Letters》2020年第5期1305-1308,共4页中国化学快报（英文版）

基　　金：the National Natural Science Foundation of China(Nos.21572002,21272005);The Research Culture Funds of Anhui Normal University;Department of Human Resources of Anhui Province for financial support。

摘　　要：This study presents a facile strategy for the formation of highly substituted butterfly 1,4-adducts/9,10-adducts via the Diels-Alder reaction of benzyne intermediates.The method achieves very good to excellent yields of the respective anthracene derivative s under mild conditions.This practical protocol is compatible with a variety of sensitive functional groups and provides access to difunctionalized bridge 1,4-adducts/9,10-adducts.

关 键 词：Bridge aromatics HDDA reaction BENZYNES Anthracene 

分 类 号：O621.25[理学—有机化学]