New strategy for production of primary alcohols from aliphatic olefins by tandem cross-metathesis/hydrogenation  

作　　者：Ruilong Jia Zhijun Zuo Xu Li Lei Liu Jinxiang Dong 

机构地区：[1]College of Chemistry and Chemical Engineering,Taiyuan University of Technology,Taiyuan 030024,China [2]Shanxi University of Traditional Chinese Medicine,Jinzhong 030619,China [3]Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province,Taiyuan University of Technology,Taiyuan 030024,China [4]School of Chemical Engineering and Light Industry,Guangdong University of Technology.Guangzhou 510006,China

出　　处：《Chinese Chemical Letters》2020年第6期1525-1529,共5页中国化学快报（英文版）

基　　金：financially supported by the National Natural Science Foundation of China(Nos.21322608 and 21276174);the Natural Science Foundation of Shanxi Province(No.201801D121055);Program for the Shanxi Young Sanjin Scholar。

摘　　要：Primary alcohols are widely used in industry as solvents and precursors of detergents.The classic methods for hydration of terminal alkenes always produce the Markovnikov products.Herein,we reported a reliable approach to produce primary alcohols from terminal alkenes combining with biomass-derived allyl alcohol by tandem cross-metathesis/hydrogenation.A series of primary alcohol with different chain lengths was successfully produced in high yields(ca.90%).Computational studies revealed that self-metathesis and hydrogenation of substrates are accessible but much slower than crossmetathesis.This new methodology represents a unique alternative to primary alcohols from terminal alkenes.

关 键 词：Primary alcohols Aliphatic olefins Allyl alcohol Cross-metathesis/hydrogenation Anti-Markovnikov regioselectivity 

分 类 号：TQ203[化学工程—有机化工]