高性能纤维的表面改性及其与橡胶基体的界面粘合性能研究进展  

Research Progress of Surface Modification of High-performance Fiber and Its Interfacial Adhesion Property with Rubber Matrix

作　　者：王磊 孙全吉 赵文博 贾丽华 张博 王文才[3] 田明[3] 范召东 WANG Lei;SUN Quanji;ZHAO Wenbo;JIA Lihua;ZHANG Bo;WANG Wencai;TIAN Ming;FAN Zhaodong(AECC Beijing Institute of Aeronautical Materials,Beijing 100095,China;Binzhou Senior Technical School,Binzhou 256600,China;Beijing University of Chemical Technology/Center of Advanced Elastomer Materials,Beijing 100029,China)

机构地区：[1]中国航发北京航空材料研究院,北京100095 [2]滨州市高级技工学校,山东滨州256600 [3]北京化工大学材料科学与工程学院/先进弹性体材料研究中心,北京100029

出　　处：《橡胶工业》2020年第7期545-550,共6页China Rubber Industry

基　　金：国家自然科学基金资助项目(51833002,51790501,51673013)。

摘　　要：从化学改性、物理改性和仿生修饰三个方面介绍高性能纤维的表面改性方法,并阐述提高高性能纤维与橡胶基体的界面粘合性能的研究进展。化学改性是通过化学活化刻蚀和引入活性基团等方式改善高性能纤维与橡胶基体的界面粘合性能,但反应不易控制,且化学改性存在环境污染问题,不易实现工业化;物理改性是通过紫外光辐照接枝以及等离子体、超声波、高能射线等处理对高性能纤维表面进行改性,可有效提高纤维与橡胶基体的界面粘合性能,值得进一步研究;新型环保的绿色浸渍体系及仿生修饰方法将在未来发挥一定的作用。In this paper,the surface modification methods of high-performance fiber were introduced from three aspects including chemical modification,physical modification and biomimetic modification,and the research progress on the improvement of the interfacial adhesion property between high-performance fiber and rubber matrix was discussed.Chemical modification was realized by chemical etching and introduction of active group,leading to the improvement of the interfacial adhesion.However,the reaction of chemical modification was not easy to control,the process usually brought environmental pollution,and it was difficult for industrialization.Physical modification was mainly to modify the surface of highperformance fiber by UV irradiation grafting and plasma,ultrasonic and high energy ray treatment,which could also enhance the adhesion property,and was worthy of further study.In addition,new environmentally friendly dipping system and biomimetic modification under development would play a role in the future.

关 键 词：高性能纤维 表面改性 橡胶 界面 粘合性能 研究进展 

分 类 号：TQ330.389[化学工程—橡胶工业]