Friede1-Crafts酰基化催化剂的研究进展  

Research progress of Friede1-Crafts acylation catalyst

作　　者：张方方 吴广文[1] 李灿 周毅博 ZHANG Fang-fang;WU Guang-wen;LI Can;ZHOU Yi-bo(Key Laboratory of New Reactor and Green Chemical,School of Chemical Engineering and Pharmacy,Wuhan Institute of Technology,Wuhan 430073,China)

机构地区：[1]武汉工程大学化工与制药学院,湖北省新型反应器与绿色化工重点实验室,湖北武汉430073

出　　处：《应用化工》2020年第7期1823-1828,1834,共7页Applied Chemical Industry

基　　金：国家自然科学基金资助项目(51773159)。

摘　　要：针对传统催化剂在选择性和可回收性等方面存在较多弊端的现状,结合近几年国内外研究进展,系统介绍了沸石分子筛、负载型催化剂、固体超强酸、离子液体、杂多酸、金属-有机框架材料等催化剂在Friedel-Crafts酰基化反应中应用进展情况,分析评估了各类催化剂在反应中的优缺点,就各类催化剂存在的实际问题提出了优化方向,并对酰基化反应催化剂的发展前景进行了展望。In view of the current situation of many disadvantages in the selectivity and recyclability of traditional catalysts,combined with the research progress at domestic and foreign in recent years,introduced systematically the progress of the application of catalysts such as zeolite molecular sieve,supported catalyst,solid super acids,ionic liquids,heteropoly acids and metal-organic framework materials in Friedel-Crafts acylation reaction,the advantages and disadvantages of various catalysts in the reaction were analyzed and evaluated.The optimization direction of various catalysts is proposed,and the development prospect of acylation catalysts is prospected.

关 键 词：Friedel-Crafts酰基化 沸石分子筛 负载型催化剂 固体超强酸 离子液体 杂多酸 金属-有机框架材料 

分 类 号：TQ225.2[化学工程—有机化工]