A collagen-based electrolyte-locked separator enables capacitor to have high safety and ionic conductivity  

作　　者：Heng Xu Yaping Wang Xuepin Liao Bi Shi 

机构地区：[1]Biomass Chemistry and Engineering Department,Sichuan University,Chengdu 610065,Sichuan,China [2]National Engineering Laboratory for Clean Technology of Leather Manufacture,Sichuan University,Chengdu 610065.Sichuan,China [3]Key Laboratory of Leather Chemistry and Engineering of Ministry of Education,Sichuan University,Chengdu 610065,Sichuan.China

出　　处：《Journal of Energy Chemistry》2020年第8期324-332,I0011,共10页能源化学（英文版）

基　　金：supported by the National Natural Science Foundation of China (21878191)。

摘　　要：The conventional liquid electrolytes(LEs) have a high level of ionic conductivity;however, they often suffer from the poor processability and safety risks of potential leakage. Although solid-state electrolytes(SSEs) can solve these inherent problems of LEs, the ionic conductivity of most SSEs is several magnitudes lower than these of LEs. Herein, we report a novel strategy by building liquid ion-transport channels in a solid framework and prepared an electrolyte-locked separator(ELS) using a collagen fiber membrane(CFm). The liquid electrolyte was primarily infiltrated in the smaller voids of CFm, and its ionic conductivity could attain to 9.0×10-3 S cm-1 when the electrolyte absorption(EA) reached up to 112.0%. After centrifuging treatment, the electrolyte retentions(ER) and ionic conductivities of ELS were 108.93% and 8.37×10-3 S cm-1, respectively, which were much higher than those of commercial cellulose separator(CS), exerting excellent liquid-locking performances. In particular, the electrical double-layer capacitors(EDLC) assembled by ELS or CS were characterized and exhibited similar electrochemical performance,demonstrating the satisfactory ability and applicability of ELS for commercial use. In addition, the ELSbased EDLC exhibited favorable flexibility with relative lower loss of capacitance under different angles of bending.

关 键 词：Collagen fiber Ionic conductivity Capillary force Electrolyte retention EDLC 

分 类 号：TB383.2[一般工业技术—材料科学与工程] TM53[电气工程—电器]