贵金属配合物催化氧化甲烷的研究进展  

Research Progress on Catalytic Oxidation of Methane by Precious Metal Complexes

作　　者：卢杰 LU Jie(School of Material Science and Engineering,University of Shanghai for Science and Technology,Shanghai 200093,China)

机构地区：[1]上海理工大学材料科学与工程学院,上海200093

出　　处：《广州化工》2020年第15期51-53,64,共4页GuangZhou Chemical Industry

摘　　要：催化氧化CH4使其C-H官能化一直是人们研究的热点,充满着挑战和机遇。有关CH4氧化的催化剂体系主要是金属配位化合物和金属分子筛结构,其中金属配位化合物的研究和应用较多。金属配合物作为一种均相催化剂被广泛应用于各种催化反应,过渡金属本身固有的结构使其能与许多配体络合生成配合物。简要综述了近年来金属配合物结构催化氧化甲烷的研究进展,以及金属配合物对C-H键活化氧化的体系和机理。Catalytic oxidation of CH4 to functionalize its C-H has always been a research hotspot,which is full of challenges and opportunities.The catalyst systems related to CH4 oxidation are mainly metal complex and metal molecular sieve structures,among which metal complex are widely studied and applied.As a homogeneous catalyst,metal complexes are widely used in various catalytic reactions.The inherent structure of transition metals enables them to complex with many ligands to form complexes.The recent research progress on the catalytic oxidation of methane by metal complex structures was reviewed,as well as the system and mechanism of metal complexes for the activation and oxidation of C-H bonds.

关 键 词：CH4 催化氧化 金属配合物 C-H键活化 

分 类 号：TQ138.2[化学工程—无机化工]