Synthesis, Structures and Room Temperature Phosphorescence of 2-(2-Methoxynaphthyl)-1H-imidazo[4,5-f][1,10]-(1)phenanthroline-Cu(I) Complexes  

作　　者：XU Jie SHANG Si-Tong LIU Xia LI Xiu-Ling 

机构地区：[1]School of Chemistry and Materials Science,Jiangsu Normal University,Xuzhou,Jiangsu 221116,China

出　　处：《Chinese Journal of Structural Chemistry》2020年第7期1314-1322,共9页结构化学（英文）

基　　金：supported financially by the National Natural Science Foundation of China(21271091)。

摘　　要：A new ligand,2-(2-methoxynaphthyl)-1H-imidazo[4,5-f][1,10]phenanthroline(mnipH),was synthesized by the condensation of 2-methoxy-1-naphthaldehyde and 5,6-diamino-1,10-phenanthroline.Then three ionic copper(I)complexes were obtained through the reactions of[Cu(MeCN)4]ClO4,mnipH and the chelating diphosphine ligands with a molar ratio of 1:1:1.The photoluminescence and the corresponding luminescent mechanism of all copper(I)complexes in the solid state were investigated at room temperature.

关 键 词：copper(Ⅰ)complexes 2-(2-methoxynaphthyl)-1H-imidazo[4 5-f][1 10]phenanthroline crystal structure photoluminescence 

分 类 号：O641.4[理学—物理化学]